Control method of neonicotinoid resistant hemiptera using spiroheterocyclic pyrrolidinedione derivatives

摘要

A method of controlling insects of the order Hemiptera, which are insects resistant to a neonicotinoid insecticide, said method comprising applying to said neonicotinoid-resistant insects a compound of formula (I): ** (See formula) ** where Q is ** (See formula) ** X, Y and Z independently of each other are C 1-4 alkyl, C 3-6 cycloalkyl, C 1-4 haloalkyl, C 1-4 alkoxy, halogen, phenyl or phenyl substituted with C 1-4 alkyl, haloC 1-4 alkyl, halogen or cyano; m and n are, independently of each other, 0, 1, 2 or 3 and m + n is 0, 1, 2 or 3; G is hydrogen, a metal, an ammonium, a sulfonium or a protecting group, where the protecting group is selected from - C (Xa) -Ra or -C (Xb) -Xc-Rb, where Xa, Xb, and Xc are independently of each other oxygen or sulfur; and Ra is H, C 1 -C 18 alkyl, C 2 -C 18 alkenyl, C 2 -C 18 alkynyl, C 1 -C 10 haloalkyl, C 1 -C 10 cyanoalkyl, C 1 -C 10 -alkyl, C 1 -C 5 -alkyl-C 1 -C 5 -alkyl-C 1 -C 1 -C 1 -C 1 -C 1 -C 1 -C 1 -C 1 -C 1 -C 1 -C 1 -C 1 -C 1 -C 1 -C 1 -C 1 -C 1 -C 1 -C 1 -C 1 -C 1 -C 1 -C 1 , alcoxiC1-C5alquiloC1-C5, C5-alqueniloxiC3-C5alquiloC1, alquinilC3-C5oxialquiloC1-C5, C5-alquiltioC1-C5alquiloC1, alquilsulfinilC1-C5alquiloC1-C5, C5-alquilsulfonilC1-C5alquiloC1, alquilidenoaminoxiC2-C8alquiloC1-C5, C5-alquilcarbonilC1- C5alquiloC1, alcoxicarbonilC1 -C5alquiloC1-C5, C5-aminocarbonilalquiloC1, alquilC1-C5aminocarbonilalquiloC1-C5, dialquilaminocarbonilC2-C8alquiloC1-C5, C5-alquilC1-C5carbonilaminoalquiloC1, N-alquilC1-C5carbonil-N-alquilC1- C5aminoalquiloC1-C5, trialquilsililC3-C6alquiloC1-C5, C5-fenilalquiloC1 (where the phenyl may be optionally substituted with C1-C3 alkyl, C1-C3 haloalkyl, C1-C3 alkoxy, C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfinyl, halogen, cyano or nitro), C1-C1-heteroarylalkyl Where the heteroaryl may be optionally substituted with C1-C3 alkyl, C1-C3 haloalkyl, C1-C3 alkoxy, C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfinyl, halogen, cyano or nitro), C2-C5-cycloalkenyl C8, phenyl or phenyl substituted with C1-C3 alkyl, haloC1-C3 alkyl, C1-C3 alkoxy, haloC1-C3 haloalkoxy, cyano or nitro, heteroaryl or heteroaryl substituted with C1-C3 alkyl, haloC1-C3 alkyl, C1-C3 alkoxy, haloC3-C1-haloalkoxy halogen, cyano or nitro; and Rb is C 1 -C 18 alkyl, C 3 -C 18 alkenyl, C 3 -C 18 alkynyl, C 2 -C 10 haloalkyl, C 1 -C 10 cyanoalkyl, C 2 -C 10 -alkyl, C 1 -C 5 -C 1 -C 1 -C 1 -C 1 -C 1 -C 1 -C 1 -C 1 -C 1 -C 1 -C 1 -C 1 -C 1 -C 1 -C 1 -C 1 -C5alquiloC1-C5, C5-alqueniloxiC3-C5alquiloC1, alquiniloxiC3-C5alquiloC1-C5, C5-alquiltioC1-C5alquiloC1, alquilsulfinilC1-C5alquiloC1-C5, C5-alquilsulfonilC1-C5alquiloC1, alquilidenoaminoxiC2-C8alquiloC1-C5, C5-alquilcarbonilC1- C5alquiloC1, alcoxicarbonilC1-C5alquiloC1 -C5, C5-aminocarbonilalquiloC1, alquilC1-C5aminocarbonilalquiloC1-C5, dialquilaminocarbonilC2-C8alquiloC1-C5, C5-alquilC1-C5carbonilaminoalquiloC1, N-alquilC1-C5carbonil-N-alquilC1- C5aminoalquiloC1-C5, trialquilsililC3-C6alquiloC1-C5, C5-fenilalquiloC1 (where The phenyl can be optionally substituted with C1-C3 alkyl, C1-C3 haloalkyl, C1-C3 alkoxy, C1-C3 haloalkoxy, C1-C3 alkylthio C1-C3 alkylsulfinyl, halogen, cyano or nitro), heteroarylC1-C3 alkyl The heteroaryl may be optionally substituted with C1-C3 alkyl, C1-C3 haloalkyl, C1-C3 alkoxy, C1-C3 haloalkoxy, C1-C3 alkylthio C1-C3 alkylsulfinyl, halogen, cyano or nitro), C3-C3-C3-C3-haloalkenyl , phenyl or phenyl substituted with C1-C3 alkyl, haloC1-C3 alkyl, C1-C3 alkoxy, haloC1-C3 haloalkoxy, cyano or nitro, heteroaryl or heteroaryl substituted with C1-C3 alkyl, haloC1-3 alkyl, C1-C3 alkoxy, haloC1-C3 haloalkoxy , cyano or nitro; R is hydrogen, C 1-6 alkyl, C 1-6 haloalkyl, C 1-6 cyanoalkyl, benzyl, (C 1-4 alkoxy) C 1-4 alkyl, (C 1-4 alkoxy) (C 1-4 alkoxy) C 1-4 alkyl or a selected group of G; and A is C 1-6 alkyl; or an agrochemically acceptable salt or an N-oxide thereof.