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APPLICATION OF A CHEMICAL COMPOSITION FOR VISCOSITY MODIFICATION OF HEAVY AND EXTRA-HEAVY CRUDE OILS

机译:化学组合物在重质和超重质原油粘度改性中的应用

摘要

The present invention is related to the application and use of a chemical composition to modify the physical properties (viscosity and interfacial tension) of heavy and extra-heavy crude oils, to increase their mobility. The chemical composition consists of the combination of systems based on ionic liquids or non-ionic liquids, depending on the character of the crude oil to be treated with, or its original modification by polymerization reaction of such liquid with oxirane; these chemicals can be dispersed in the aqueous or organic media; in the first case the composition that is dispersed in the aqueous phase is used at temperatures between 5 and 90 °C, with pressures from 1 up to about 340.23 atm (i.e., 5,000 psi), and under acid-base er within the pH range of 4 to12.5; though one prefers a basic scheme for certain crude oils, i.e., a pH between 7 and 12.5; however, other crudes are better handled under neutral conditions or even acidic conditions, for example those with a pH between 4 and 7; in the second case, the dispersant is organic and consists of a composition of at least one generic solvent and up to three, together with a surfactant that can be based on amphiphile, i.e., sulphonic moiety with hydrocarbon chain, with 12 to 16 carbons and a cation based on alkylamine, in the proportions mentioned in the body of the invention. The applications of interest may occur at various stages during operation with heavy crude oils, from the stage of extraction from the well in the field, or during the transport of crude oil in surface pipelines, or even in the well discharge pipelines; Its use can be performed using a mixing unit in addition of pumping unit with enough pressure to inject the chemical composition, which provokes a substantial reduction of the original fluid viscosity, thus improving te operation during the stages of production, transportation and processing of the heavy and extra-heavy crudes. The chemical composition consists of a combination of systems based on ionic and non-ionic liquids, which may be pure or modified, mixed in dispersing agent, either aqueous or organic, depending on the nature of the crude to be treated with, together with a surfactant, where the composition is used in conditions of temperature between and 100 °C, at pressures from 1 atm (14.7 psi) up to about 680.2 atm (10,000 psi).
机译:本发明涉及化学组合物的应用和用途,以改变重质和超重质原油的物理性质(粘度和界面张力),以增加其流动性。化学成分由基于离子液体或非离子液体的系统的组合组成,这取决于要处理的原油的特性,或通过这种液体与环氧乙烷的聚合反应进行的原始改性;这些化学物质可以分散在水性或有机介质中;在第一种情况下,分散在水相中的组合物的使用温度为5至90°C,压力为1至最高约340.23 atm(即5,000 psi),并且在pH范围内的酸碱下使用为4至12.5;尽管有人更喜欢某些原油的基本方案,即pH在7至12.5之间;但是,其他原油在中性条件甚至酸性条件下(例如pH值为4至7的条件)都可以更好地处理;在第二种情况下,分散剂是有机的,由至少一种通用溶剂和最多三种的组合物以及可以基于两亲性的表面活性剂(即具有烃链的磺酸部分)组成,具有12至16个碳原子,以及以本发明主体中提到的比例的基于烷基胺的阳离子。感兴趣的应用可能发生在重质原油运行期间的各个阶段,从油田的开采阶段开始,或者在地面管道甚至井排管道中运输原油期间;它的使用可以通过使用一个混合装置以及一个具有足够压力以注入化学成分的泵送装置来进行,这可以大大降低原始流体的粘度,从而在重油的生产,运输和加工阶段提高操作效率和超重原油。化学成分由基于离子液体和非离子液体的系统组成,这些系统可以是纯净的或改性的,并与要处理的原油的性质混合在水性或有机分散剂中,具体取决于要处理的原油的性质。表面活性剂,其中该组合物在介于1 atm(14.7 psi)至约680.2 atm(10,000 psi)的压力下在100至100°C的温度条件下使用。

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