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MEASURING CELL FOR RAMAN SPECTROSCOPY AT A SOLID-LIQUID INTERFACE AND USES THEREOF

机译:固液界面上拉曼光谱的细胞测定及其用途

摘要

According to the invention, provision is made of a measuring cell for Raman spectroscopy at a solid-liquid interface. The measuring cell essentially consists of a main body and at least parts of a working electrode, reference electrode and counter electrode. In the measuring cell according to the invention, a part of the working electrode forms the base of the measuring cell that is in contact with an electrolyte, with this part of the working electrode being electrically contacted at a location in the measuring cell that is not in contact with the electrolyte. This brings about an avoidance of unwanted potential shifts already at very low electrolyte quantities and an improved quality, resolution and standard deviations of the spectra recorded by the measuring cell over the prior art. Arranging the second part of the working electrode in a recess on the lower side of the main body brings about simple and fast cleaning of the measuring cell. Moreover, uses of the measuring cell according to the invention are proposed.
机译:根据本发明,提供了一种在固液界面处用于拉曼光谱的测量单元。测量池主要由主体和至少一部分工作电极,参比电极和反电极组成。在根据本发明的测量池中,工作电极的一部分形成与电解质接触的测量池的底部,而工作电极的这一部分在测量池中未接触的位置处电接触。与电解液接触。这避免了在非常低的电解质量下就已经存在的不希望的电位偏移,并且避免了由测量单元记录的光谱相对于现有技术的改进的质量,分辨率和标准偏差。将工作电极的第二部分布置在主体下侧的凹槽中,可实现对测量池的简单,快速清洁。此外,提出了根据本发明的测量池的用途。

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