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Method for preparing N-doped carbon shell protected ordered PtFe nanoparticle and ordered PtFe nanoparticle obtained thereof and uses thereof

机译:N掺杂碳壳保护的有序PtFe纳米粒子的制备方法及其获得的有序PtFe纳米粒子及其用途

摘要

The present invention relates to a method for producing aligned platinum alloy nanoparticles having a uniform size by a nitrogen-doped carbon coating layer, wherein the platinum alloy nanoparticles in more detail align with the platinum precursor and the iron precursor, Comprising the steps of: preparing nanoparticles; adsorbing platinum iron nanoparticles on the surface of the carbon support to produce carbon-supported platinum iron nanoparticles; coating the surfaces of the carbon-supported platinum iron nanoparticles with polypodamine and heat treating In the heat treatment step, the nitrogen-doped carbon coating layer formed by the carbonization of the polypodamine inhibits aggregation of the platinum nano-particles to form uniform particles, and the formation of the ordered lattice-structure platinum nano-particles . In addition, when the aligned platinum iron nanoparticles according to the present invention is applied as a reducing electrode catalyst of a fuel cell, there is an advantage that excellent performance and stability can be secured while reducing the amount of platinum loading.
机译:本发明涉及一种通过掺杂氮的碳涂层制备尺寸均匀的取向铂合金纳米颗粒的方法,其中所述铂合金纳米颗粒与铂前体和铁前体更详细地取向,包括以下步骤:纳米粒子将铂铁纳米颗粒吸附在碳载体的表面上以产生碳负载的铂铁纳米颗粒;用聚多巴胺涂覆碳负载的铂铁纳米颗粒的表面并进行热处理在热处理步骤中,通过聚多巴胺的碳化形成的氮掺杂碳涂层抑制了铂纳米颗粒的聚集,从而形成均匀的颗粒,并且形成有序晶格结构的铂纳米粒子。另外,当将根据本发明的取向的铂铁纳米颗粒用作燃料电池的还原电极催化剂时,具有可以在降低铂负载量的同时确保优异的性能和稳定性的优点。

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