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METHOD OF COLLOID SYNTHESIS OF ULTRA-SMALL PHOTOLUMINESCENT NANOPARTICLES OF THE CORE / SHELL STRUCTURE

机译:核/壳结构的超小型光致发光纳米粒子的胶体合成方法

摘要

FIELD: nanotechnologies.;SUBSTANCE: usage: for the production of photoluminescent nanoparticles, or quantum dots (QD), of ultra-small size. Essence of the invention lies in the fact that in the method of colloidal synthesis of photoluminescent nanoparticles of an ultra-small size of the core / shell structure, including the synthesis of cores of photoluminescent nanoparticles by injecting the core components into an environment of organic solvents, purification of the cores from the reaction mixture and subsequent buildup of the epitaxial shell of photoluminescent nanoparticles in the environment of organic solvents, ultrafast, not more than for 5 seconds, stopping of the reaction of synthesis of nanoparticle cores in the early stages of growth is conducted, and before building up the epitaxial shell of nanoparticles, the nanoparticle cores are purified by exclusion chromatography.;EFFECT: technical result of the proposed invention consists in the production of quantum dots of an ultra-small size, up to 2 nm in diameter, with reproducible high-homogeneous optical properties and physical dimensions.;11 cl
机译:领域:纳米技术;物质:用途:用于生产超小尺寸的光致发光纳米粒子或量子点(QD)。本发明的本质在于以下事实:胶体合成核/壳结构的超小尺寸的光致发光纳米粒子,包括通过将核成分注入有机溶剂的环境中来合成光致发光纳米粒子的核。 ,从反应混合物中纯化核心,以及随后在有机溶剂环境中以超快的速度(不超过5秒)建立光致发光纳米粒子的外延壳,从而在生长的早期阶段停止了纳米粒子核心的合成反应进行;并且在构建纳米颗粒的外延壳之前,通过排阻色谱法纯化纳米颗粒核。效果:本发明的技术结果在于产生了超小尺寸的量子点,其最大粒径为2nm。直径,具有可重现的高度均一的光学特性和物理尺寸。; 11 cl

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