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Continuous synthesis method and continuous synthesis apparatus for core-shell structured nanoparticles of metal core / oxide shell and core-shell structured nanoparticles

机译:金属核/氧化物壳的核壳结构纳米粒子的连续合成方法和连续合成装置

摘要

This invention addresses the problem of providing a method and apparatus for continuously synthesizing nanoparticles in few processes and without causing variation in particle size or aggregation, as well as providing a core-shell structure nanoparticle. This invention concerns a continuous synthesis method for core-shell structure nanoparticles, a continuous synthesis apparatus, and core-shell structure nanoparticles synthesized by this continuous synthesis method and/or this continuous synthesis apparatus, wherein: the continuous synthesis method for core-shell structure nanoparticles continuously synthesizes metal nanoparticles having a diameter of 1-100 nM through an initial stage flow-type reaction tube (3) comprising at least a single stage flow-type reaction tube, hydrolyzes an oxide precursor in a subsequent stage flow-type reaction tube (10) comprising at least a single stage flow-type reaction tube, and uniformly heats at least the flow-type reaction tube (3) through microwaves; and the continuous synthesis apparatus has initial and subsequent stage flow-type reaction tubes (3, 10), and has a means for uniformly heating at least the flow-type reaction tube (3) through microwaves, the flow-type reaction tube (3) being a reaction tube for metal core synthesis, and the other flow-type reaction tube (10) being a reaction tube for oxide shell synthesis.
机译:本发明解决的问题是提供一种在很少的过程中连续合成纳米颗粒且不引起粒径或聚集变化的方法和设备,以及提供核-壳结构纳米颗粒。本发明涉及用于核-壳结构纳米粒子的连续合成方法,连续合成装置和通过该连续合成方法和/或该连续合成装置合成的核-壳结构纳米粒子,其中:核-壳结构的连续合成方法纳米粒子通过包括至少一个单级流动型反应管的初始级流动型反应管(3)连续地合成直径为1-100nM的金属纳米颗粒,在后续级的流动型反应管中水解氧化物前体。 (10)包括至少一个单级的流动型反应管,并且通过微波均匀地加热至少该流动型反应管(3);连续合成装置具有初期和后期的流动型反应管(3、10),并具有通过微波至少均匀地加热流动型反应管(3)的装置,该流动型反应管(3) )是用于金属核合成的反应管,另一个流动型反应管(10)是用于氧化物壳合成的反应管。

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