首页> 外国专利> TANDEM QUADRUPOLE MASS SPECTROMETER

TANDEM QUADRUPOLE MASS SPECTROMETER

机译:串联四极质谱仪

摘要

A dwell time calculation table (51a) showing a correspondence relation between a CID gas pressure inside a collision cell (31) and a dwell time for data collection is stored in a processing condition parameter memory (51) of a controller (50). In the table (51a), as the CID gas pressure becomes higher, the dwell time becomes longer. When an instruction to execute an MRM measurement mode is given, the controller (50) determines the dwell time in accordance with the currently set CID gas pressure, and controls a data collector (41) to accumulate detection signals from an ion detector (34) during the determined dwell time and obtain the accumulated value. If the CID gas pressure inside the collision cell (31) is high, a decrease in ion speed becomes remarkable, and the rising of the ion intensity becomes slow. However, if the dwell time becomes long, influences of the slow rising on the accumulated value are relatively reduced, and the accuracy of the accumulated value is enhanced. Accordingly, the quantitative accuracy can be enhanced.
机译:在控制器(50)的处理条件参数存储器(51)中存储有表示碰撞室(31)内的CID气压与数据收集的停留时间的对应关系的停留时间计算表(51a)。在表(51a)中,随着CID气压变高,停留时间变长。当给出执行MRM测量模式的指令时,控制器(50)根据当前设置的CID气压确定停留时间,并控制数据收集器(41)累积来自离子检测器(34)的检测信号。在确定的停留时间内,获得累加值。如果碰撞室31内的CID气体压力高,则离子速度的下降变得显着,离子强度的上升变慢。但是,如果停留时间变长,则缓慢上升对累积值的影响相对减小,并且累积值的精度提高。因此,可以提高定量精度。

著录项

  • 公开/公告号EP2924425B1

    专利类型

  • 公开/公告日2019-09-11

    原文格式PDF

  • 申请/专利权人 SHIMADZU CORPORATION;

    申请/专利号EP20120888969

  • 发明设计人 UEDA MANABU;

    申请日2012-11-22

  • 分类号H01J49/24;H01J49/42;G01N27/62;G01N30/72;H01J49;

  • 国家 EP

  • 入库时间 2022-08-21 12:31:47

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