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ELECTROLYTE FOR ELECTROLYTE CIRCULATION-TYPE BATTERY, AND ELECTROLYTE CIRCULATION-TYPE BATTERY SYSTEM
ELECTROLYTE FOR ELECTROLYTE CIRCULATION-TYPE BATTERY, AND ELECTROLYTE CIRCULATION-TYPE BATTERY SYSTEM
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机译:用于电解液循环型电池的电解液和电解液循环型电池系统
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摘要
Provided is an electrolyte for a flow battery, the electrolyte being supplied to a flow battery, in which a total concentration of ions of elements of groups 1 to 8 and ions of elements of groups 13 to 16 in the fifth period of the periodic table, and ions of elements of groups 1, 2, and 4 to 8 and ions of elements of groups 13 to 15 in the sixth period of the periodic table, the ions being impurity element ions involved in generation of a gas containing elemental hydrogen, is 610 mg/L or less, a concentration of vanadium ions is 1 mol/L or more and 3 mol/L or less, a concentration of free sulfuric acid is 1 mol/L or more and 4 mol/L or less, a concentration of phosphoric acid is 1.0 × 10-4 mol/L or more and 7.1 × 10-1 mol/L or less, a concentration of ammonium is 20 mg/L or less, and a concentration of silicon is 40 mg/L or less. When a charging and discharging test is performed by circulating and supplying the electrolyte to the flow battery under specific conditions, a generation rate of hydrogen is less than 10 cc/h/m2 and a generation rate of hydrogen sulfide is less than 5.0 × 10-3 cc/h/m2, the hydrogen and the hydrogen sulfide being generated in a negative electrode of the flow battery during charging and discharging.
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机译:提供了一种用于液流电池的电解质,该电解质被供应至液流电池,其中在周期表的第五周期中,第1至8族元素的离子和第13至16族元素的离子的总浓度,在元素周期表的第六周期中,第1、2和4至8族元素的离子以及第13至15族元素的离子是610,它们是与生成含元素氢的气体有关的杂质元素离子mg / L以下,钒离子浓度为1 mol / L以上至3 mol / L以下,游离硫酸的浓度为1 mol / L以上至4 mol / L以下,浓度为磷酸为1.0×10 -4 Sup> mol / L以上且7.1×10 -1 Sup> mol / L以下,铵的浓度为20 mg / L以下,并且硅的浓度为40mg / L以下。当通过在特定条件下循环并向液流电池供应电解液来执行充电和放电测试时,氢气的产生速率小于10 cc / h / m 2 Sup>和氢气的产生速率硫化物小于5.0×10 -3 Sup> cc / h / m 2 Sup>,氢和硫化氢在充放电期间在液流电池的负极中生成。
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