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Lithium-containing transition metal composite oxide, positive electrode active material for lithium secondary battery, positive electrode for lithium secondary battery, lithium secondary battery, and method for producing lithium-containing transition metal composite oxide
Lithium-containing transition metal composite oxide, positive electrode active material for lithium secondary battery, positive electrode for lithium secondary battery, lithium secondary battery, and method for producing lithium-containing transition metal composite oxide
To provide a lithium-containing transition metal complex oxide having good output characteristics. A lithium-containing transition metal complex oxide comprising secondary particles formed by aggregation of primary particles capable of doping and dedoping lithium ions. (1) It is represented by the following formula (I). Li [Lix (Ni (1-y-z-w) CoyMnzMw) 1-x] O2 (I) (2) From the X-ray photoelectron spectroscopy analysis, the surface of the secondary particle and the inside of the secondary particle The γ value of the surface of the secondary particle is calculated as γ1, and the γ value of the inside of the secondary particle is γ2, the γ1 and γ2 satisfy the condition of the following formula (II). 0.3 ≦ γ1 / γ2 ≦ 1.0 (II) 【Selection chart】 None
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机译:提供具有良好输出特性的含锂过渡金属复合氧化物。一种含锂的过渡金属复合氧化物,其包含通过聚集能够掺杂和去掺杂锂离子的初级颗粒而形成的次级颗粒。 (1)由下式(I)表示。 Li [Lix(Ni(1-yzw)CoyMnzMw)1-x] O2(I)(2)根据X射线光电子能谱分析,二次粒子的表面和二次粒子的内部计算出二次粒子的表面为γ1,二次粒子内部的γ值为γ2,γ1和γ2满足下式(II)的条件。 0.3≤γ1/γ2≤1.0(II)【选择表】无
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