首页> 外国专利> Solution Polymerized Styrene-Butadiene Rubber-Polyurethane Elastomer Material for High Performance Tire and Preparation Method Thereof

Solution Polymerized Styrene-Butadiene Rubber-Polyurethane Elastomer Material for High Performance Tire and Preparation Method Thereof

机译:高性能轮胎的固溶聚合苯乙烯-丁二烯橡胶-聚氨酯弹性体材料及其制备方法

摘要

A solution polymerized styrene-butadiene rubber-polyurethane elastomer material and a preparation method thereof are provided. The elastomer material is prepared by performing cast molding on a soft segment and a hard segment in a mass ratio of 100:(20-50); the soft segment includes hydroxyl-terminated solution polymerized styrene-butadiene moiety rubber prepared by an anionic polymerization; the hard segment comprises isocyanate, a small-molecule polyol chain extender and a cross-linking agent; and the soft segment has a molecular weight of 1000-8000 and a glass-transition temperature of −20° C. to −30° C. According to the elastomer material in the disclosure, the hydroxyl-terminated solution polymerized styrene-butadiene rubber is introduced to serve as the soft segment on the basis of synthesis of the traditional polyurethane elastomer, so that the glass-transition temperature of the polyurethane elastomer is regulated, defects such as poor high temperature resistance and undesirable wet-skid resistant grip ability of an existing polyurethane tire are overcome.
机译:提供了一种溶液聚合的苯乙烯-丁二烯橡胶-聚氨酯弹性体材料及其制备方法。弹性体材料是通过在软链段和硬链段上以质量比100:(20-50)进行浇铸成型而制备的;所述软链段包括通过阴离子聚合制备的羟基封端的溶液聚合的丁苯橡胶。硬链段包括异氰酸酯,小分子多元醇扩链剂和交联剂。所述软链段的分子量为1000-8000,玻璃化转变温度为-20℃至-30℃。根据本发明的弹性体材料,所述羟基封端的溶液聚合的丁苯橡胶为在合成传统聚氨酯弹性体的基础上引入软质链段,从而调节了聚氨酯弹性体的玻璃化转变温度,存在诸如耐高温性差和现有的不希望的耐湿滑抓地力等缺点。聚氨酯轮胎被克服。

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