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Solution-polymerized styrene-butadiene rubber-polyurethane elastomer material for high performance tires and method of making

机译:用于高性能轮胎的溶液聚合苯乙烯-丁二烯橡胶-聚氨酯弹性体材料及其制造方法

摘要

The present invention discloses a solution polymerized styrene-butadiene rubber-polyurethane elastomer material for a high-performance tire and a preparation method thereof. The elastomer material is prepared by performing cast molding on a soft segment and a hard segment in a mass ratio of 100:(20-50); the soft segment is hydroxyl-terininated solution polymerized styrene-butadiene rubber prepared by an anionic polymerization; the hard segment comprises isocyanate, a small-molecule polyol chain extender and a cross-linking agent; and the soft segment has a molecular weight of 1000-8000 and a glass-transition temperature of -20°C to -30°C According to the elastomer material in the invention, the hydroxyl-terminated solution polymerized styrene-butadiene rubber is introduced to serve as the soft segment on the basis of synthesis of the traditional polyurethane elastomer, so that the glass-transition temperature of the polyurethane elastomer is regulated, defects such as poor high temperature resistance and undesirable wet-skid resistant grip ability of an existing polyurethane tire are overcome, and the prepared tire has excellent comprehensive application property.
机译:本发明公开了一种用于高性能轮胎的溶液聚合的苯乙烯-丁二烯橡胶-聚氨酯弹性体材料及其制备方法。弹性体材料是通过在软链段和硬链段上以质量比100:(20-50)进行浇铸成型而制备的;所述软链段是通过阴离子聚合制备的羟基终端的溶液聚合的丁苯橡胶。硬链段包括异氰酸酯,小分子多元醇扩链剂和交联剂。所述软链段的分子量为1000-8000,玻璃化转变温度为-20℃至-30℃。根据本发明的弹性体材料,将羟基封端的溶液聚合的丁苯橡胶引入在传统聚氨酯弹性体合成的基础上,作为软链段,从而调节了聚氨酯弹性体的玻璃化转变温度,存在诸如现有聚氨酯轮胎的耐高温性差和不希望的耐湿滑抓地力等缺陷克服了上述问题,制备的轮胎具有优异的综合应用性能。

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