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HYDROGEN SENSITIVE FILMS AND SENSORS PRODUCED THEREFROM

机译:氢敏感膜和传感器由此产生

摘要

Described are sensors and methods of detecting hydrogen gas. The sensor includes a polymer matrix and a dye molecule in an amount sufficient such that exposure of the polymer matrix to hydrogen gas causes a change in a spectroscopic property of the dye molecule wherein the spectroscopic property includes at least one of color, absorbance, or luminescence. The polymer matrix may further include a catalyst, such as a transition metal, sulfonated Wilkinson's catalyst, colloidal Pt, sulfonated iridium cyclooctadiene triphenylphosphine, sulfonated rhodium cyclooctadiene triphenylphosphine, sulfonated ruthenium triphenylphosphine, or combinations thereof. Embodiments of the sensor may further include a gas permeable, water impermeable membrane, an outer covering, or combinations thereof.
机译:描述了检测氢气的传感器和方法。所述传感器包括足以使聚合物基质暴露于氢气引起染料分子的光谱性质变化的量的聚合物基质和染料分子,其中光谱性质包括颜色,吸收率或发光中的至少一种。 。聚合物基体可以进一步包括催化剂,例如过渡金属,磺化的威尔金森氏催化剂,胶体Pt,磺化铱环辛二烯三苯基膦,磺化铑环辛二烯三苯基膦,磺化钌三苯基膦或它们的组合。传感器的实施例可以进一步包括透气,不透水的膜,外壳或其组合。

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