Trifluorodioxyl used to control phytotoxin fungi

摘要

1. Property 1: compound (1) with formula property,or N-oxides, or agriculturally acceptable salts thereof, where: A is phenyl or a 5- or 6-membered aromatic heterocycle, wherein the ring member atoms of the aromatic heterocycle include, in addition to carbon atoms , 1, 2, 3, or 4 heteroatoms selected from N, O, and S as ring member atoms; and wherein the phenyl ring or aromatic heterocycle is unsubstituted or substituted with 1, 2, 3 or 4 identical or different RA groups; wherein RA is halogen, cyano, C₁₋₆-alkyl, C₁₋₆-haloalkyl, C₁₋₆-alkoxy or C₁₋₆-haloalkoxy; W is -NR²- (C = O) - #,-NR - (C 3DS) - 23-NR -S (3DO) - 23- (C = O) -NR²- #,- (C = S) -NR²- #,-S (3DO) -NR - 23-NR - (C 3DO) -NR - 23-83099 - (C = O) - 35;-NR - (C 3DS) -NR - 23-83099 - (C = s) - 2 -;-NR -S (3DO) -NR - 23-O- (C = O) -NR²- #,-O- (C = S) -NR²- #,-NR - (C 3DO) -O- 23 o -NR - (C 3DS) -O- 233. Position, indicating position, connected to R1;P is 0, 1 or 2; R: es-n (rs74919) 8322;wherein R²ᵃ is independently selected from the group consisting of hydrogen, OH, C₁₋₆-alkyl, C₂₋₆-alkenyl, C₂₋₆-alkynyl, C₃₋₈-cycloalkyl, C₃₋₈-cycloalkenyl, C₁₋₆-alkoxy , C₁₋₄-alkoxy-C₁₋₄-alkyl and C₁₋₆-alkylthio; and wherein any of the aliphatic or cyclic groups is unsubstituted or substituted with 1, 2, 3 or up to the maximum possible amount of identical or different radicals selected from the group consisting of halogen, hydroxy, oxo, cyano, C₁₋₆- alkyl, C₁₋₆-alkoxy and C₃₋₈-cycloalkyl; R⁵ is hydrogen, C₁₋₆-alkyl, C₁₋₆-alkoxy, C₂₋₆-alkenyl,C₂₋₆-alkynyl, C₁₋₆-alkoxy, C₃₋₈-cycloalkyl, C₃₋₈-cycloalkenyl, C₃₋₈-cycloalkyl-C₁₋₆-alkyl, phenyl-C₁₋₄-alkyl or phenyl; and wherein any one of the aliphatic or cyclic groups is unsubstituted or substituted with 1, 2, 3 or up to the maximum possible amount of identical or different radicals selected from the group consisting of halogen, cyano, C₁₋₆-alkyl and C₁₋ ₆-alkoxy; R¹ is C₁₋₆-alkyl, C₃₋₈-cycloalkyl, C₃₋₈-cycloalkenyl, C₂₋₆-alkenyl, C₂₋₆-alkynyl, C₁₋₆-alkoxyimino-C₁₋₄-alkyl, C₂₋₆-alkenyloxyimino- C₁₋₄-alkyl,C₂₋₆-alkynyloxyimino-C₁₋₄-alkyl, phenyl-C₁₋₄-alkyl, phenyl-C₁₋₄-alkenyl, phenyl-C₁₋₄-alkynyl, heteroaryl-C₁₋₄-alkyl, phenyl, naphthyl or a heterocycle 3- or 10-membered saturated, partially unsaturated or aromatic mono- or bicyclic, wherein the ring member atoms of said mono- or bicyclic heterocycle include, in addition to the carbon atoms, other 1, 2, 3 or 4 heteroatoms selected from N, O, and S as ring member atoms; and wherein the heteroaryl group in the heteroaryl-C₁₋₄-alkyl group is a 5- or 6-membered aromatic heterocycle, wherein the ring member atoms of the heterocyclic ring include,1. Except for carbon atoms, 1, 2, 3 or 4 heteromorphic atoms selected from n or s are used as ring atoms; among these atoms, none of the above pairing or cycling groups is replaced or replaced by 1, 2, 3 or as many r74919 same or different groups as possible; O R1 is a double ring equation of carbon thyroid (2), where c749191 and c74955 are carbon atoms as bridgeheads; X is a direct link or a different type of group selected from c8322a group;-CH₂-CH₂-,- (CH) -- (CH) --CH=CH---CH₂-CH = CH-,-CH = CH-CH₂- and -CH = CH-CH = CH-;Y and Z are independent of each other,They were selected from a group of - ch832222.-CH₂-CH₂-,- (CH) -- (CH) --CH=CH---CH₂-CH = CH-,CH = CH-CH₂- and -CH = CH-CH = CH-;O R1 is a three cycle carbon thyroid (3), in which c74919 and c74955 are carbon atoms as bridges; X is a direct link, or a group of different elements selected from ch8322 -, group;-CH₂-CH₂-,- (CH) -- (CH) --CH=CH---CH₂-CH = CH-,-CH = CH-CH₂- and -CH = CH-CH = CH-;And Z, independent of each other,They were selected from a group of - ch832222.-CH₂-CH₂-,- (CH) -- (CH) --CH=CH---CH₂-CH = CH-,-CH = CH-CH₂- and -CH = CH-CH = CH-;a. Y and Z groups are connected with c749191 and c74955 bridge carbon atoms;T was selected from a group consisting of - ch832222.-CH₂-CH₂-,- (CH) -- (CH) --CH=CH---CH₂-CH = CH-,-CH = CH-CH₂- and -CH = CH-CH = CH-;Group t adds carbon atoms of each group y and Z, provided that R1 is tricyclic carbide (3) of the formula,In X is a simple direct link or a different combinationGroup T and group Z were independent,They were selected from a group consisting of - ch832222 - ch832222;- (CH) -- (CH) --CH=CH---CH₂-CH = CH-,-CH = CH-CH₂- and -CH = CH-CH = CH-;and where the groups of formula (2) or (3) are connected to group W through one of the ring carbon atoms; and wherein the groups of formula (2) or (3) are unsubstituted or substituted with 1, 2, 3, 4 or up to the maximum possible amount of radicals selected from the group consisting of oxo, hydroxy, halogen, C₁₋₃ -alkyl, C₁₋₃-haloalkyl, C₃₋₆-cycloalkyl, vinylidene and dichlorovinylidene; or R¹ and one of the two groups R²ᵃ,1. With the nitrogen atom of 749191 and the adjacent groups between the nitrogen atom and R1 group,They form a saturated or partially unsaturated single cycle or double cycle composed of 3 to 10 members. In this cycle, except for two nitrogen atoms and one or more carbon atoms, no other heteroatom or one, two or three non heteroatoms are selected as atoms independent of N, or as atoms of ring components; e. To replace or replace the heterocycle with the same or different group of r74919, or R1 and r83099;Together with the nitrogen atoms to which they are linked, and any group that may exist between them, these groups lie between the nitrogen atom and group R1,a. Forming a saturated or partially unsaturated single cycle or double cycle consisting of 3 to 10 members, in which, in addition to one nitrogen atom and one or more carbon atoms, there are also 1, 2 or 3 heteroatoms selected from n, or s as a ring atom; and one or two ch8322 selected from the heterocycle; It can be replaced by one or two independent groups C (= O) - and C (= s).and wherein the heterocycle is unsubstituted or substituted with 1, 2, 3, 4 or up to the maximum possible amount of identical or different radicals selected from the group consisting of halogen, cyano, C₁₋₆-alkyl, C₁₋₆-haloalkyl , C₁₋₆-alkoxy and C₁₋₆-haloalkoxy; R¹ᵃ is halogen, oxo, cyano, NO₂,Oh, SH, nh832222,C₁₋₆-alkyl, C₁₋₆-haloalkyl, C₁₋₆-alkoxy, C₁₋₆-haloalkoxy, C₁₋₆-alkylthio, C₁₋₆-haloalkylthio, C₃₋₈-cycloalkyl, -NHSO₂-C₁₋₄-alkyl , (C = O) -C₁₋₄-alkyl, C (= O) -C₁₋₄-alkoxy, C₁₋₆-alkylsulfonyl, hydroxy-C₁₋₄-alkyl, C (= O) -NH₂,C (3DO) -NH (C -alquilo)C₁₋₄-alkylthio-C₁₋₄-alkyl, amino-C₁₋₄-alkyl, C₁₋₄-alkylamino-C₁₋₄-alkyl, di-C₁₋₄-alkylamino-C₁₋₄-alkyl, aminocarbonyl-C₁₋ ₄-alkyl or C₁₋₄-alkoxy-C₁₋₄-alkyl; m is 0 or 1; R³,R830808 is independently selected,from the group consisting of hydrogen, halogen, cyano, C₁₋₄-alkyl, C₁₋₄-alkenyl, C₁₋₄-alkynyl, C₁₋₄-haloalkyl and C₁₋₄-alkoxy; or R³ and R⁴,together with the carbon atom to which they are attached, they form a 3- to 7-membered saturated carbocycle or a 3- to 6-membered saturated heterocycle; wherein the saturated heterocycle includes, in addition to the carbon atoms, 1, 2, or 3 heteroatoms selected independently from the group consisting of N, O, and S as ring member atoms; and wherein said N-ring member atom is replaced with the RN group; wherein RN is hydrogen, C₁₋₆-alkyl or halogen; and wherein the S-ring member atom is unsubstituted or substituted with 1 or 2 oxo radicals;In this case, one or two saturated carbohydrate or saturated heterocyclic ch832222 groups may be replaced by one or two selected groups independent of - C (= O) - and - C (= s);and wherein the carbon ring member atoms of the saturated carbocycle or saturated heterocycle are unsubstituted or substituted with a total amount of 1, 2, 3, 4 or up to the maximum possible amount of identical or different radicals selected from the group consisting in halogen, cyano, C₁₋₆-alkyl, C₁₋₆-alkoxy and C₃₋₈-cycloalkyl; with the exception of the compounds of formula (1),Where m is 0 and W is - (C = O) - NR2 -.