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1-(1R,2S,5R)-(-)-menthoxymethyl-3-tetradecylimidazolium saccharinate, method for producing and applications

机译:1-[(1R,2S,5R)-(-)-薄荷氧甲基] -3-十四烷基咪唑糖精盐,制备方法和应用

摘要

the subject of saccharin is 1 - [(1r, 2s, 5r) - (-) - mentoksymetylo] - 3 - tetradecyloimidazoliowy, belonging to chiralnych ionic liquids, model 1,containing optically active group in the cation part of the (1r, 2s.5r) - (-) - menthol combined bridge with methylene nitrogen type pirolowego imidazole in position n - 1 and tetradecyl chain combined with the nitrogen type pirydyniowego imidazole in position n - 3a chain alkyl containing fourteen carbon atoms, while part sacharynianowy anion anion.the notification includes means to generate monocyklicznego saccharin 1 - [(1r, 2s, 5r) - (-) - mentoksymetylo] - 3 - tetradecyloimidazoliowego, model 1, which is that chiralnych chloride 1 - [(1r,, 2s, 5r) - (-) - mentoksymetylo] - 3 - tetradecyloimidazoliowy model 2 undergo exchange reaction with sodium sacharynianem, compared the middle ru00f3wnomolowemu, temperature of 273,15 k to 373,15,in the presence of an organic solvent or in water.the application also relates to application of saccharin 1 - [(1r, 2s, 5r) - (-) - mentoksymetylo] - 3 - tetradecyloimidazoliowy, belonging to chiralnych ionic liquids.model 1 as a measure of performance antyelektrostatycznym.
机译:糖精的主题是1-[(1r,2s,5r)-(-)-薄荷基]-3-十四烷基碘咪唑啉基,属于手性离子液体,模型1,在(1r,2s的阳离子部分中含有旋光性基团.5r)-(-)-薄荷醇在n-1位的亚甲基氮型吡咯咯烷咪唑和十四烷基链与在n-3a位的氮型pirydyniowego咪唑结合的含14个碳原子的烷基烷基结合的桥联分子,而部分为char型阴离子。通知中包含产生单环糖精1-[((1r,2s,5r)-(-)-mentoksymetylo]-3-十四烷基咪唑啉酮的方法,模型1,即手性氯化物1-[[(1r ,, 2s,5r)- (-)-薄荷脑-3-十四烷基咪唑并与模型中的char基钠发生交换反应,在有机溶剂存在或在水中的情况下,中间r温度为273,15 k至373,15。也与糖的应用有关1-[(1r,2s,5r)-(-)-mentoksymetylo]-3-十四烷基咪唑啉代,属于手性离子液体。模型1是对性能的测量。

著录项

  • 公开/公告号PL231804B1

    专利类型

  • 公开/公告日2019-04-30

    原文格式PDF

  • 申请/专利权人 POLITECHNIKA WROCŁAWSKA;

    申请/专利号PL20170420448

  • 发明设计人 FEDER-KUBIS JOANNA;

    申请日2017-02-10

  • 分类号C07D233/60;C07C31/135;C07D275/06;C09K3/16;

  • 国家 PL

  • 入库时间 2022-08-21 12:01:18

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