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A method for the production of hydrogen by a steam reforming reaction of hydrothermal liquefaction liquid from macro algae using a catalyst of perovskite composite structure

机译:用钙钛矿复合结构催化剂由大型藻类进行水热液化液的蒸汽重整反应生产氢气的方法

摘要

The present invention relates to a catalyst for the stream reforming reaction of marine algae-derived hydrothermal liquefied raw materials and a method of producing hydrogen using the same. The present invention produces hydrogen from raw materials generated through a hydrothermal liquefaction reaction from marine algae by the steam reforming reaction of marine algae-derived hydrothermal liquefied raw materials using M1M2_xO_y catalyst of a Ni-supported perovskite complex structure. The present invention has effects of: being used as a non-food energy source which is not a food source without a necessity of cultivated land by using seaweed biomass unlike conventional grain and starch biomass as a raw material for hydrogen production; having a high productivity of one-year cycle and an excellent carbon dioxide reducing effect compared to other biomass; having higher reaction activity compared to Ni/Al_2O having a commercially available catalyst structure as hydrogen is produced by the steam reforming reaction of marine algae-derived hydrothermal liquefaction raw materials using M1M2_xO_y catalyst of a Ni-supported perovskite complex structure; and continuously maintaining a high hydrogen conversion rate even after long time steam reforming reaction.
机译:本发明涉及用于衍生自海藻的水热液化原料的物流重整反应的催化剂和使用该催化剂生产氢气的方法。本发明通过使用Ni担载的钙钛矿配合物结构的M1M2_xO_y催化剂,通过由海藻衍生的水热液化原料的蒸汽重整反应,由通过海藻的水热液化反应产生的原料产生氢。本发明具有以下效果:与传统的谷物和淀粉生物质作为制氢原料相比,通过使用海藻生物质被用作非食物能源,其不是不需要耕地的食物来源;与其他生物质相比,具有一年周期的高生产率和出色的二氧化碳减排效果;通过使用Ni担载的钙钛矿配合物结构的M1M2_xO_y催化剂,通过海藻衍生的水热液化原料的水蒸气重整反应,与具有市售的催化剂结构的Ni / Al_2O相比具有更高的反应活性。即使经过长时间的水蒸气重整反应,也连续保持高的氢转化率。

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