首页> 外国专利> RAW COPOLYESTER MATERIAL FOR AMORPHOUS FILM, HEAT-SHRINKABLE POLYESTER-BASED FILM, HEAT-SHRINKABLE LABEL, AND PACKAGE

RAW COPOLYESTER MATERIAL FOR AMORPHOUS FILM, HEAT-SHRINKABLE POLYESTER-BASED FILM, HEAT-SHRINKABLE LABEL, AND PACKAGE

机译:适用于非透明薄膜,可热收缩基于聚酯的薄膜,可热收缩标签和包装的原始共聚酯材料

摘要

A problem to be solved by the present invention is to provide a heat-shrinkable polyester film which exhibits a high heat-shrinking rate in a width direction, which exhibits a small natural shrinking rate in a longitudinal direction, and which exhibits small changes in the shrinking rate before and after the aging treatment, and to provide a raw material for preparing the heat-shrinkable polyester film as such.;An amorphous copolymerized polyester raw material for a film, characterized that, it satisfies the following requirements (1) to (4), and is used for producing a film:(1) The raw material contains ethylene terephthalate as a main constituent component, and contains from 18 % by mol to 30% by mol of neopentyl glycol when a total amount of a glycol component in a total polyester resin component is taken as 100% by mol; (2) The raw material contains from 8% by mol to 16% by mol of a constituent unit derived from diethylene glycol in the total amount (100% by mol) of the glycol component in the total polyester resin component; (3) The raw material has an intrinsic viscosity of from 0.70 dl/g to 0.86 dl/g; and (4) The raw material has a melt viscosity of 200Pa·S or less, when measured at a shear rate of 6080/S at 250°C.
机译:本发明要解决的问题是提供一种可热收缩的聚酯膜,该膜在宽度方向上表现出高的热收缩率,在纵向上表现出小的自然收缩率,并且其表现出小的变化。老化处理前后的收缩率的降低,从而提供用于制备这样的热收缩聚酯膜的原料。膜用非晶态共聚聚酯原料,其特征在于,满足以下(1)〜( 4),用于生产薄膜:(1)原料中,以对苯二甲酸乙二酯为主要成分,以聚酯树脂成分总量中的二醇成分总量为100重量%时,含有18〜30摩尔%的新戊二醇。摩尔(2)原料中,聚酯树脂成分总量中的二醇成分的总量(100摩尔%)中含有8〜16摩尔%的源自二甘醇的构成单元。 (3)原料的特性粘度为0.70dl / g〜0.86dl / g。 (4)在250℃下以6080 / S的剪切速率测定时,原料的熔融粘度为200Pa·S以下。

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