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ULTRAHIGH FLUX GAS-SELECTIVE NANOPOROUS CARBON MEMBRANE AND MANUFACTURING METHOD THEREOF

机译:超高通量气体选择性纳米碳膜及其制造方法

摘要

The present relates to a nanoporous carbon membrane manufacturing method comprising coating a block copolymer film with hydrophilic and hydrophobic blocks, on a sacrificial non-porous substrate so as to prepare an block copolymer film coated foil, transferring the block copolymer film on a porous support, pyrolizing the block copolymer film to form a nanoporous carbon film, wherein the transfer step consists in a wet-transfer process comprising placing the block copolymer film coated foil in an etchant bath in an etching chamber and the porous support above the height of said etching bath, etching the underlying sacrificial foil of block copolymer film coated foil, raising the height of the etching bath above the porous support, bringing the free-floating etched block copolymer film on top of the porous support, and lowering the etching bath height below the porous support so as to deposit the copolymer film on top of the porous support.
机译:本发明涉及一种纳米多孔碳膜的制造方法,该方法包括在牺牲性无孔基材上涂布具有亲水性和疏水性嵌段的嵌段共聚物膜,从而制备嵌段共聚物膜涂布箔,将该嵌段共聚物膜转移至多孔性支撑体上,将嵌段共聚物膜热解以形成纳米多孔碳膜,其中转移步骤包括湿转移过程,该湿转移过程包括将涂覆有嵌段共聚物膜的箔片置于蚀刻室中的蚀刻剂浴中,并将多孔载体置于所述蚀刻浴剂的高度之上。 ,蚀刻下面的嵌段共聚物膜涂布箔的牺牲箔,将蚀刻浴的高度提高到多孔载体上方,将自由浮动的蚀刻后的嵌段共聚物膜置于多孔载体的顶部,并将蚀刻浴的高度降低到多孔以下载体以将共聚物膜沉积在多孔载体的顶部。

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