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Graphite negative electrode material for non-aqueous secondary batteries, negative electrode for non-aqueous secondary batteries and non-aqueous secondary batteries

机译:非水系二次电池用石墨负极材料,非水系二次电池用负极和非水系二次电池

摘要

PROBLEM TO BE SOLVED: To provide a graphite-based negative electrode material having excellent quick charging characteristics. Further, the present invention provides a negative electrode for a non-aqueous secondary battery and a non-aqueous secondary battery obtained by using this graphite-based negative electrode material. SOLUTION: In the electron spin resonance method measured by using microwaves in the X band region, it has an absorption spectrum derived from a carbon radical appearing near g = 2.0, and a resonance absorption curve at a temperature of 4.8 K. A graphite-based negative electrode material for a non-aqueous secondary battery having a half-value width ΔH1 / 2 of 2.7 (mT) or more and a Raman R value of 0.21 or more represented by the following formula 1. Equation 1: [Raman R value] = [Intensity ID of peak PD near 1360 cm-1 in Raman spectrum analysis] / [Intensity IG of peak PG near 1580 cm-1 in Raman spectrum analysis] [Selection diagram] None
机译:解决的问题:提供具有优异的快速充电特性的石墨基负极材料。另外,本发明提供非水系二次电池用负极以及使用该石墨系负极材料得到的非水系二次电池。解决方案:在电子自旋共振方法中,使用X波段区域的微波进行测量,它具有源自出现在g = 2.0附近的碳自由基的吸收光谱,以及在4.8 K的温度下的共振吸收曲线。石墨基非水系二次电池用负极材料,其半值宽度ΔH1/ 2为2.7(mT)以上,且拉曼R值为0.21以上,由下式1表示。式1:[拉曼R值] = [拉曼光谱分析中1360 cm-1附近的峰PD的强度ID] / [拉曼光谱分析中1580 cm-1附近的PG峰的强度IG] [选择图]无

著录项

  • 公开/公告号JP2020167153A

    专利类型

  • 公开/公告日2020-10-08

    原文格式PDF

  • 申请/专利权人 三菱ケミカル株式会社;

    申请/专利号JP20200047970

  • 发明设计人 原田 隆;関 敬一;平原 聡;

    申请日2020-03-18

  • 分类号H01M4/587;H01M4/133;C01B32/20;

  • 国家 JP

  • 入库时间 2022-08-21 11:35:24

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