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Device and method for calorimetrically measuring sorption processes

机译:用于量热测量吸附过程的装置和方法

摘要

The aim of the invention is to provide a commercially usable and inexpensive device and method with which a sorption enthalpy can be measured in a simple manner. This is achieved by a device for calorimetrically measuring sorption processes, comprising a sorption cell for receiving a sample, the sorption cell having a volume for filling with a sorption gas, and comprising a reference cell likewise for filing with the sorption gas. A measurement gas volume is arranged around the sorption cell for receiving a reference gas, and the reference cell is surrounded by a reference gas volume, which is likewise provided for receiving the reference gas. A gas connection is provided between the sorption cell and the reference cell in order to conduct sorption gas into the sorption cell and the reference cell such that a sorption reaction occurs with the sample in the sorption cell. Furthermore, a device is provided for measuring pressure differences between the measurement gas volume and the reference gas volume in order to carry out a calorimetric measurement of the sorption process on the sample in the sorption cell on the basis of a volume change of the reference gas in the measurement gas volume.
机译:发明内容本发明的目的是提供一种商业上可用且便宜的装置和方法,利用该装置和方法可以以简单的方式测量吸附焓。这通过用于量热测量吸附过程的设备来实现,该设备包括用于接收样品的吸附池,该吸附池具有用于填充吸附气体的容积,并且还包括参考池,该参考池同样用于与吸附气体一起填充。在吸附池周围布置有用于接收参考气体的测量气体体积,并且参考池被参考气体体积包围,参考气体体积同样被设置用于接收参考气体。在吸附池和参比池之间提供气体连接,以将吸附气体引导到吸附池和参比池中,使得在吸附池中与样品发生吸附反应。此外,提供了一种用于测量测量气体体积与参考气体体积之间的压力差的装置,以便基于参考气体的体积变化对吸附池中的样品进行吸附过程的量热测量。在测量气体量中。

著录项

  • 公开/公告号US10605753B2

    专利类型

  • 公开/公告日2020-03-31

    原文格式PDF

  • 申请/专利权人 WATERS GMBH;

    申请/专利号US201314381946

  • 申请日2013-02-14

  • 分类号G01N25/38;G01N25/48;G01K17/06;G01K19;

  • 国家 US

  • 入库时间 2022-08-21 11:28:26

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