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Thermosetting Starch Adhesive For Wood-based Panel and Preparation Method Therefor

机译:人造板用热固性淀粉胶粘剂及其制备方法

摘要

The present disclosure discloses a thermosetting starch adhesive for a wood-based panel and a preparation method therefor, and belongs to the technical field of preparation of adhesives. In the present disclosure, starch is used as a main raw material, and after acid hydrolysis thereof, a semi-continuous seed emulsion polymerization method is adopted to improve control of monomer polymerization stability. After grafting is completed, a cross-linking monomer with polymerizable double bonds and condensable methylol functional groups is added for copolymerization. The cross-linking monomer is also added in a semi-continuous manner. After the cross-linking reaction is completed, the reaction mixture is gelatinized and incubated, and finally a thermosetting adhesive which can be used for bonding of hot-pressed wood-based panels is obtained. The adhesive of the present disclosure has the properties of two-step cross-linking and high-temperature rapid cross-linking curing, good film formation, good heat resistance, and strong cohesion. With a hot-pressing process in an appropriate coating manner, appropriate temperature and pressure, the resultant wood-based panels have all their properties superior over those of Class II wood-based panels, and they can be widely used in decoration of hot-pressed woods, and bonding of wood-based panels and plywoods.
机译:本发明公开了一种用于人造板的热固性淀粉胶粘剂及其制备方法,属于胶粘剂制备技术领域。在本发明中,以淀粉为主要原料,酸水解后,采用半连续种子乳液聚合法,以提高对单体聚合稳定性的控制。接枝完成后,添加具有可聚合双键和可缩合羟甲基官能团的交联单体进行共聚。交联单体也以半连续方式添加。交联反应完成后,将反应混合物胶凝并温育,最后获得可用于粘合热压木板的热固性粘合剂。本公开的粘合剂具有两步交联和高温快速交联固化的性质,良好的成膜性,良好的耐热性和强的内聚力。通过以适当的涂覆方式,适当的温度和压力进行热压工艺,所得人造板的所有性能均优于II类人造板,并且可以广泛用于热压装饰中。木材,以及人造板和胶合板的粘合。

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