首页> 外国专利> PROCEDURE FOR SYNTHESIS OF CARBON HYDRADES FROM SYNTHESE GAS IN THE PRESENCE OF A COBALT-BASED CATALYST BATTERED IN A MESOPOROUS OXID MATRIX AND OBTAINED FROM AT LEAST A COLLOID PROLOID

PROCEDURE FOR SYNTHESIS OF CARBON HYDRADES FROM SYNTHESE GAS IN THE PRESENCE OF A COBALT-BASED CATALYST BATTERED IN A MESOPOROUS OXID MATRIX AND OBTAINED FROM AT LEAST A COLLOID PROLOID

机译:存在于氧化钴基质中的钴基催化剂存在且至少从胶体蛋白质中获得时,由合成气合成碳氢化物的方法

摘要

The invention relates to a method for synthesizing linear paraffinic hydrocarbons from a feed including carbon monoxide and dihydrogen in the presence of a catalyst including a mesoporous oxide matrix and a mass percentage of cobalt of between 0.5 and 60%, expressed in wt.% of metal relative to the total weight of said catalyst, said catalyst being prepared according to a preparation method including at least the steps of: a) mixing in an aqueous or hydro-organic solvent at least one molecular precursor including cobalt and at least one colloidal precursor of said mesoporous oxide matrix including at least one element X selected from the group consisting of silicon, aluminum, titanium, zirconium, cerium and mixtures thereof, said molecular precursor including cobalt being made soluble in said aqueous or hydro-organic solvent; b) atomizing the mixture obtained in step a) to result in the formation of spherical droplets; c) drying said spherical droplets to obtain solid particles at a temperature of between 10 and 300°C; d) activating said solid particles via reductive treatment so as to form cobalt nanoparticles having a valence state of 0.
机译:本发明涉及一种在催化剂存在下由包括一氧化碳和二氢的进料合成线性链烷烃的方法,该催化剂包括中孔氧化物基质和钴的质量百分比为0.5-60%,以金属的重量%表示。相对于所述催化剂的总重量,所述催化剂是根据至少包括以下步骤的制备方法制备的:a)在水性或氢有机溶剂中混合至少一种包括钴和至少一种胶体前体的分子前体。所述中孔氧化物基体,其包含至少一种选自硅,铝,钛,锆,铈及其混合物的元素X,所述包括钴的分子前体可溶于所述水性或水性有机溶剂中; b)将步骤a)中获得的混合物雾化以形成球形液滴; c)干燥所述球形液滴,以在10至300℃之间的温度下获得固体颗粒; d)通过还原处理活化所述固体颗粒,从而形成价态为0的钴纳米颗粒。

著录项

  • 公开/公告号DK3380586T3

    专利类型

  • 公开/公告日2020-03-30

    原文格式PDF

  • 申请/专利权人 IFP ENERGIES NOUVELLES;

    申请/专利号DK20160794567T

  • 发明设计人 CHAUMONNOT ALEXANDRA;FECANT ANTOINE;

    申请日2016-11-07

  • 分类号C10G2;B01J23/74;B01J23/75;B01J23/89;B01J29/03;B01J35/10;B01J37;B01J37/03;B01J37/18;

  • 国家 DK

  • 入库时间 2022-08-21 11:17:42

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