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PROCESS FOR THE TRANS-SELECTIVE HYDROBORATION OF INTERNAL ALKYNES
PROCESS FOR THE TRANS-SELECTIVE HYDROBORATION OF INTERNAL ALKYNES
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机译:内部炔烃的选择加氢过程
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摘要
The present invention refers to a process for the trans-selective hydroboration of internal alkynes and the so-obtained products. The inventive process makes use of a borane of the formula X1X2BH selected from the group of dialkyl boranes or di(alkoxy)boranes which are reacted with the internal alkynes in the presence of a cyclyopentadienyl-coordinated ruthenium catalyst.
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机译:本发明涉及用于内部炔烃和如此获得的产物的反式选择性硼氢化的方法。本发明的方法使用式X 1 X 2 BH的硼烷,其选自二烷基硼烷或二(烷氧基)硼烷,其在环戊二烯基配位的钌催化剂的存在下与内部炔烃反应。
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