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Method for recovering HCI from a HCI containing gas stream

机译:从含HCl气流中回收HCl的方法

摘要

The invention pertains to a method for recovering HCl from a HCl containing gas stream wherein a HCl containing gas stream with a temperature of -20 to 25ºC is provided to an adiabatic absorptionunit where it is contacted with water as an absorbent, resulting in the formation of a top gas stream and a aqueous HCl product solution, wherein the temperature of the top gas stream is at least 70ºC and wherein the aqueous HCl product solution has a HCl concentration in the range of 5-20 wt.%. It is preferred for the HCl-containing gas stream to be derived from a hydrogenation step wherein a feed comprising monochloroacetic acid (MCA) and dichloroacetic acid (DCA) is reacted with hydrogen to form a HCl-containing gas stream and a product stream comprising MCA and a reduced amount of DCA. The HCl product solution is preferably diluted to a concentration of 1-8 wt.%, and the diluted solution is used as absorbent in a second absorption step, wherein HCl is absorbed from a further HCl-containing gas stream to form a second aqueous HCl solution. The further HCl-containing gas stream is preferably derived from a chlorination step wherein acetic acid is reacted with chlorine, resulting in the formation of the further HCl-containing gas stream and a feed comprising monochloroacetic acid (MCA) and dichloroacetic acid (DCA).
机译:本发明涉及一种从含HCl的气流中回收HCl的方法,其中将温度为-20至25℃的含HCl的气流提供给绝热吸收单元,在该绝热吸收单元中与作为吸收剂的水接触,从而形成水。顶部气流和HCl产物水溶液,其中所述顶部气流的温度为至少70℃,并且其中所述HCl产物水溶液的HCl浓度为5-20重量%。含HCl的气流优选衍生自氢化步骤,其中使包含一氯乙酸(MCA)和二氯乙酸(DCA)的进料与氢气反应以形成含HCl的气流和包含MCA的产物流。并减少了DCA的数量。优选将HCl产物溶液稀释至1-8重量%的浓度,并且该稀释溶液在第二吸收步骤中用作吸收剂,其中从另外的含HCl的气流中吸收HCl以形成第二HCl水溶液。解。所述另外的含HCl的气流优选衍生自氯化步骤,其中乙酸与氯反应,导致形成另外的含HCl的气流和包含一氯乙酸(MCA)和二氯乙酸(DCA)的进料。

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