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METHOD OF PREPARING YTTRIA STABILIZED ZIRCONIA (YSZ) NANOSOL HAVING EXCELLENT DISPERSIBILITY

机译:具有优异分散性的稳定氧化钇(YSZ)纳米溶胶的制备方法

摘要

The present invention relates to a method of preparing a yttria stabilized zirconia nanosol having excellent dispersibility, the method comprising the steps of: (a) mixing a ZrOCl2·8H2O sol and a Y(NO3)3·6H2O sol and adding a basic material thereto to regulate the pH thereof; (b) subjecting the sol obtained in step (a) to a hydrothermal reaction to prepare yttria stabilized zirconia (YSZ) nanoparticles; and (c) conducting a treatment for improving the dispersibility of a nanosol with the YSZ nano particles dispersed therein. According to the present invention, a YSZ sol with excellent dispersability can be produced by adding various silane coupling agents, acids/bases, polymers, and surfactants to nanosized YSZ synthesized via a hydrothermal reaction, and as such, by resolving the coagulation issue indicated as a problem in applications of nanosized YSZ, the nanosized YSZ sol thus prepared can achieve further excellent properties when applied as a heat-shielding coating material and the like.
机译:本发明涉及具有优异的分散性的氧化钇稳定的氧化锆纳米溶胶的制备方法,该方法包括以下步骤:(a)混合ZrOCl 2 ·8H 2 O溶胶和Y(NO 3 3 ·6H 2 O溶胶并向其中添加碱性物质以调节其pH。 (b)将步骤(a)中获得的溶胶进行水热反应以制备氧化钇稳定的氧化锆(YSZ)纳米颗粒; (c)进行用于提高分散有YSZ纳米粒子的纳米溶胶的分散性的处理。根据本发明,可以通过将各种硅烷偶联剂,酸/碱,聚合物和表面活性剂添加到通过水热反应合成的纳米级YSZ中,并通过解决指示为的凝结问题,来制备具有优异分散性的YSZ溶胶。纳米YSZ的应用中存在的问题是,如此制备的纳米YSZ溶胶在用作隔热涂料等时可以实现进一步优异的性能。

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