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A process for the production of plasma sprayable yttria stabilized zirconia (ysz) and plasma sprayble ysz powder produced thereby

机译:等离子体可喷涂氧化钇稳定的氧化锆(ysz)的生产方法以及由此生产的等离子体可喷涂ysz粉末

摘要

Most widely used commercial zirconia powders are composed of porous particles 10-105µm and 45-75µm in size. Furthermore, these powders are mixtures of tetragonal, cubic, and monoclinic modifications, which indicate the heterogeneous distribution of the stabilizing yttria dopant in finished powder not suitable for Solid oxide fuel cell applications. Most of the methods reported in the prior art employs an additional agglomeration step which makes the process more expensive and laborious, Present invention provides a simple and economical process for the preparation of plasma grade yttria stabilized zirconia powder useful for applications in solid oxide fuel cells (SOFC) and thermal barrier coatings without the agglomeration step. Plasma grade yttria stabilized zirconia powders of present invention are prepared at different mole % of yttria varying from 3 to 12 %. Finished powder has particle size varying between 33-51 µm and flowabilty of 30-54 seconds per 50gm of powder having particle morphology ranging from almost spherical to blocky angular shape.
机译:市场上使用最广泛的氧化锆粉末由10-105µm和45-75µm的多孔颗粒组成。此外,这些粉末是四方,立方和单斜晶变体的混合物,表明稳定的氧化钇掺杂剂在成品粉末中的不均匀分布,不适用于固体氧化物燃料电池应用。现有技术中报道的大多数方法都采用了额外的附聚步骤,这使该方法更加昂贵和费力。本发明提供了一种简单经济的方法来制备可用于固体氧化物燃料电池的等离子级氧化钇稳定的氧化锆粉末( SOFC)和隔热涂层,无需附聚步骤。制备本发明的等离子级氧化钇稳定的氧化锆粉末,其氧化钇的不同摩尔%为3-12%。制成的粉末的粒度在33-51 µm之间变化,每50克粉末的流动性为30-54秒,其粉末形态范围从几乎球形到块状。

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