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Interlayer for protecting anode of rechargeable battery preparation method thereof and lithium metal battery comprising the same

机译:用于保护充电电池阳极的中间层及其制备方法和包括该中间层的锂金属电池

摘要

It is an object of the present invention to provide an electrolyte system for maintaining energy density and extending battery life of a lithium metal negative electrode based secondary battery. The ultimate application goal of this technology is a variety of anodes, such as transition metal oxides, sulfur, and cathodes used in lithium-ion secondary batteries with high energy density, as well as existing lithium-ion batteries used in future unmanned electric vehicles and grid energy storage systems. Together with lithium metal. It will also contribute to the development of drones such as drones, which are emerging recently. The present invention is expected to secure the global competitiveness of the related secondary battery and electrochemical capacitor industry. Especially when dealing with materials with high density energy, the recent research on safety has attracted attention as one of the core research. The reason for this is that safety is lowered due to high energy density in product commercialization. In particular, it is inevitable to secure high energy density battery safety due to the social and technological winds caused by smartphone ignition. In particular, the upcoming next-generation batteries have to be researched and confirmed on the safety of the battery and the battery handling system since the energy density of the existing lithium-ion battery is substantially at least 2 to 8 times higher. Accordingly, the present invention forms a three-dimensional metal current collector with a pore structure pattern on the anode material thin film, and inhibits the production of dendrites through rapid diffusion and stable electrodeposition of lithium ions using the lithium metal electrode and By preventing side reactions between the electrolyte solutions, it can be applied as a negative electrode for a lithium metal secondary battery having stable and high coulombic efficiency.
机译:本发明的目的是提供一种电解质系统,该电解质系统用于维持能量密度并延长基于锂金属负极的二次电池的电池寿命。这项技术的最终应用目标是各种阳极,例如高能量密度锂离子二次电池中使用的过渡金属氧化物,硫和阴极,以及未来无人驾驶电动汽车和汽车中使用的现有锂离子电池。电网储能系统。与锂金属一起。它还将为无人机的发展做出贡献,例如最近兴起的无人机。期望本发明确保相关二次电池和电化学电容器工业的全球竞争力。特别是在处理具有高密度能量的材料时,最近的安全性研究作为核心研究之一已引起关注。其原因是由于产品商业化中的高能量密度而降低了安全性。特别是,由于智能手机点火引起的社会和技术风,不可避免地要确保高能量密度电池的安全性。特别地,由于现有锂离子电池的能量密度实质上高出至少2至8倍,因此必须对电池和电池处理系统的安全性进行研究和确认。因此,本发明在负极材料薄膜上形成具有孔结构图案的三维金属集电体,并且通过使用锂金属电极的锂离子的快速扩散和稳定的电沉积以及通过防止副反应来抑制树枝状晶体的产生。在电解质溶液之间,它可以用作具有稳定和高库仑效率的锂金属二次电池的负极。

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