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ABS ABS COMPOSITIONS HAVING AN IMPROVED SURFACE FOLLOWING STORAGE IN A WARM-HUMID ENVIRONMENT

机译:在温暖潮湿的环境中,ABS ABS组合物在存储后的表面质量得到改善

摘要

The present invention provides A) 0 to 98 parts by weight based on the sum of A and B, a mixture of several thermoplastic polymers different from B or one of them, B) 2 to 100 parts by weight of B1) emulsification based on the sum of A and B At least one graft polymer prepared by the polymerization process, B2) optionally at least one graft polymer prepared by the bulk polymerization, suspension polymerization or solution polymerization process, B3) optionally at least one rubber-free A polymer composition containing a containing vinyl (co) polymer and C) 0 to 30 parts by weight of at least one conventional polymer additive, wherein the sum of the parts by weight of A and B is 100. The present invention provides a composition comprising (i) at least one composition comprising a cation selected from the group consisting of alkali metals, alkaline earth metals and aluminum and anions selected from the group consisting of chloride, sulfates, nitrates, phosphates, acetates and formates Inorganic salts at a concentration of 100 to 5000 mg / kg based on the composition, and (ii) the salts in the composition are provided in fully dissolved form or in the form of amorphous or crystalline inclusions having a size of less than 60 μm. It is characterized by. The disclosed polymer compositions are characterized by an improved surface even after being stored in a warm and humid environment, and optionally after partial or complete application to further surface treatment steps such as painting, film insert molding, vacuum metallization or electroplating. It is particularly suitable for the production of molded articles or molded articles having class A surface requirements and high-gloss finishes.
机译:本发明提供A)基于A和B之和的0至98重量份,几种不同于B或它们之一的热塑性聚合物的混合物,B)基于A至B的2至100重量份B1)乳化。 A和B的总和。至少一种通过聚合方法制备的接枝聚合物,B2)任选地至少一种通过本体聚合,悬浮聚合或溶液聚合方法制备的接枝聚合物,B3)任选地至少一种不含橡胶的A聚合物组合物含乙烯基(共)聚合物和C)0至30重量份的至少一种常规聚合物添加剂,其中A和B的重量份之和为100。本发明提供了一种组合物,其包含(i)至少一种组合物,其包含选自碱金属,碱土金属和铝的阳离子以及选自氯,硫酸盐,硝酸盐,磷酸盐,乙酸盐和甲酸盐的阴离子基于组合物的浓度为100至5000 mg / kg的无机盐,以及(ii)组合物中的盐以完全溶解的形式或尺寸小于60μm的无定形或结晶夹杂物形式提供。它的特点是。所公开的聚合物组合物的特征在于即使在温暖和潮湿的环境中存储之后,以及任选地在部分或完全施加到进一步的表面处理步骤(例如涂漆,薄膜嵌件成型,真空金属化或电镀)之后,表面也得到改善。它特别适合于生产模制品或具有A级表面要求和高光洁度的模制品。

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