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The Potential of Graphene Nanoplatelets in the Development of Smart and Multifunctional Ecocomposites

机译:石墨烯纳米型在智能和多功能eCocoC复合材料开发中的潜力

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摘要

Graphene and its derivatives have shown outstanding potential in many fields and textile/composites industry are not an exception. Giving their extraordinary properties, Graphene Nanoplatelets (GNPs) are excellent candidates for providing new functionalities to fibers and composites. In this work, natural fabrics (flax) were functionalized with chitosan (CS) based polymeric formulations of GNPs to develop fibrous systems with electrical properties as well as other functionalities. One of the greatest disadvantages of using carbon-based materials for fabrics’ impregnation is their difficult dispersion. Therefore, several polymers were used as matrices, binding and dispersive agents including chitosan, polyethylene glycol (PEG), and glycerol. All the systems were characterized using several techniques that demonstrated the presence and incorporation of the GNPs onto the composites. Besides their characterization, considering their use as smart materials for monitoring and sensing applications, electrical properties were also evaluated. The highest value obtained for electrical conductivity was 0.04 S m−1 using 2% of GNPs. Furthermore, piezoresistive behavior was observed with Gauge Factor (GF) of 1.89 using 0.5% GNPs. Additionally, UV (ultraviolet) protection ability and hydrophobicity were analyzed, confirming the multifunctional behavior of the developed systems extending their potential of application in several areas.
机译:石墨烯及其衍生物在许多领域中显示出突出的潜力,纺织/复合材料行业并不是一个例外。赋予其非凡的性质,石墨烯纳米片(GNPS)是用于为纤维和复合材料提供新功能的优异候选者。在这项工作中,用基于壳聚糖(CS)的GNP的聚合物制剂官能化的天然织物(亚麻)官能化,以开发具有电性能以及其他功能的纤维体系。使用碳基材料的织物浸渍的最大缺点之一是它们难以分散的。因此,将几种聚合物用作基质,结合和分散剂,包括壳聚糖,聚乙二醇(PEG)和甘油。所有系统都是使用几种技术表征,所述技术证明了GNP的存在和掺入复合材料。除了他们的表征外,考虑到它们用作监测和传感应用的智能材料,还评估了电性能。用于导电率获得的最高值,使用2%的GNPS为0.04 s M-1。此外,使用0.5%GNPS的仪表因子(GF)观察压阻性行为。另外,分析了UV(紫外线)保护能力和疏水性,确认发达系统的多功能行为在几个区域中延伸其应用潜力。

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