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Flow Improvers for Heavy Crude Oil Transport in Pipe

机译:管道中重质原油运输的流动改进剂

摘要

The transportation of heavy oil is challenging as the oil has high viscosity and heavy components like asphaltenes. By finding an effective flow improver the transporting could be less demanding and more cost effective. Asphaltene aggregation is suspected to have an effect on the viscosity of the crude oil as asphaltenes act as colloids in the crude oil, and aggregate together. Traditionally it is accepted that asphaltenes are stabilized by other polar components, resins. Resin has a polar and a non-polar part that disperses the asphaltenes in the crude oil, and the structure of resins seems to be important. The polarity of the asphaltenes is believed to be an important parameter for finding a solvent that could have a stabilizing effect as resins. Solvents with active molecules as alcohol and ketone might have the potential to reduce the viscosity of a heavy oil by interacting with the asphaltenes. To find a solvent to be used as a flow improver the solubility parameters of Hildebrand and Hansen has been looked into. Different solvents already tested by other have been looked into, and the solubility parameters between these have been compared. Hildebrand solubility parameters around 22 MPa0.5 seem to be a good start point for finding a chemical that can be used as a flow improver. In the experimental work three different crude oils have been tested by adding thirteen different types of solvents in various amounts. The solvents were added in small amounts (≤ 3 wt %) to study the solvent s effect to reduce the viscosity by dispersing the asphaltenes in the oil. The analyses used to detect the effect from the studied solvents are Karl Fischer titration, viscometer, rheometer, near infrared spectroscopy and nuclear magnetic resonance spectroscopy. The three different crude oils that have been tested can be characterized as relatively viscous, with viscosity values ranging from 345 to 4152 mPa s at the actual test temperatures. The glycols have an opposite effect, they increased the viscosity in all tested crude oils. Some of the added solvents, as 1-hexanol and 2-butanone, have reduced the viscosity of the crude oil. However, this seems to be rather a diluting effect than a clear effect of dispersing the asphaltenes and thereby reducing the viscosity. The commercial products used in the experimental work, one viscosity reduction chemical and three asphaltene dispersant chemicals, reduced the viscosity mainly because of dilution. Using a glycol, 1-hexanol or 2-butanone in small amounts (≤ 3 wt %) as flow improver are not preferred instead of additive a lighter petroleum product, as naphtha, to reduce the viscosity of the oil.
机译:重油的运输具有挑战性,因为该油具有高粘度和重组分,如沥青质。通过找到有效的流量改进剂,运输的要求可能会降低,并且更具成本效益。沥青质被认为对原油的粘度有影响,因为沥青质在原油中起胶体作用并聚集在一起。传统上,人们公认沥青质可以通过其他极性组分树脂来稳定。树脂具有将沥青质分散在原油中的极性和非极性部分,并且树脂的结构似乎很重要。沥青质的极性被认为是寻找可以作为树脂具有稳定作用的溶剂的重要参数。具有活性分子(如醇和酮)的溶剂可能具有通过与沥青质相互作用降低重油粘度的潜力。为了找到用作流动改进剂的溶剂,已经研究了希尔德布兰德和汉森的溶解度参数。研究了已经由其他公​​司测试过的不同溶剂,并比较了它们之间的溶解度参数。 Hildebrand溶解度参数约为22 MPa0.5,似乎是寻找可用作流动改进剂的化学品的良好起点。在实验工作中,通过添加十三种不同类型的溶剂(量不同)对三种不同的原油进行了测试。少量(≤3 wt%)添加溶剂以研究溶剂通过将沥青质分散在油中来降低粘度的效果。用于检测所研究溶剂影响的分析方法是卡尔·费休滴定法,粘度计,流变仪,近红外光谱和核磁共振光谱。经过测试的三种不同的原油可以表征为相对粘稠,在实际测试温度下的粘度值范围为345至4152 mPa s。乙二醇具有相反的作用,它们增加了所有测试原油中的粘度。一些添加的溶剂(例如1-己醇和2-丁酮)降低了原油的粘度。然而,这似乎是稀释作用,而不是明显的分散沥青质从而降低粘度的作用。实验工作中使用的市售产品,一种降低粘度的化学药品和三种沥青质分散剂的化学药品,降低粘度的主要原因是稀释。不优选使用少量(≤3 wt%)的乙二醇,1-己醇或2-丁酮作为流动改进剂,而不是添加轻质石油产品(如石脑油)以降低油的粘度。

著录项

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    Fagerdal Stine;

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  • 年度 2014
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  • 原文格式 PDF
  • 正文语种 eng
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