Electrochemical and Spectroelectrochemical Studies of Some Coordination Compounds in High Oxidation States

摘要

The effect of various axial anions on the reactivity and solution structure of manganese(III)tetraphenylporphyrins has been studied using voltammetric and spectroelectrochemical methods. Several rhodotorulic acid complexes of vanadium in the +4 and +5 oxidation state have been identified and their solution chemistry explored using these same methods. The ligand, N,N'-di(2-aminomethylpyridyl)malondiamide and its Ni(II), Cu(II), and Co(III) complexes have been prepared and characterized, and preliminary electrochemical studies have been conducted. (ERA citation 09:017015)