Core Spline Method for Solution of Quantum-Mechanical Systems of Differential Equations for Bound States

摘要

A generalization of the core spline method is given in the case of solution of the general bound state problem for a system of M linear differential equations with coefficients depending on the spectral parameter. The recursion scheme for construction of basic splines is described. The wave functions are expressed as linear combinations of basic splines, which are approximate partial solutions of the system. The spectral parameter (the eigenvalue) is determined from the condition for existence of a nontrivial solution of a (MxM) linear algebraic system at the last collocation point. The nontrivial solutions of this system determine (M - 1) coefficients of the linear spans, expressing the wave functions. The last unknown coefficient is determined from a boundary (or normalization) condition for the system. The computational aspects of the method are discussed, in particular, its concrete algorithmic realization used in the RODSOL program. The numerical solution of the Dirac system for the bound states of a hydrogen atom is given is an example. 10 refs.; 1 fig.; 2 tabs. (Atomindex citation 18:091335)