THE THERMODYNAMICS OF SEVERAL LIGHT METAL OXIDES, HALIDES AND OXYHALIDES.

摘要

The report presents thermodynamic data on the thermodynamic properties of the oxyhalides of boron and aluminum. The thermodynamic properties including the standard heats of formation and standard entropies of formation for compounds stable only at high temperatures including BOF, (BOF)3, AlOF, (BOCl)3and HBO2were completed and have been published in the open literature. A study of the reaction B2O3(l) +BCl3(g) = 3BOCl(g) was completed in the temperature range of 1234K to 1389K. A study of the reaction A12O3(l) + AlC13(g)= 3AlOCl(g) in the temperature range 2300K to 2400K was also completed. (Author)