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Facile Cleavage of the Mo=Mo Bond in Reactions between (Mo2(OBut)6 and Aryl Azides and Molecular Oxygen

机译：（mo2（OBut）6和芳基叠氮化物与分子氧之间反应中mo = mo键的简易裂解

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Product I is structurally related to (MoMe2(NBu(+))2)2 recently characterized by Nujent and Harlow; Product II, the tert-butyl ester of molybdic acid, is the first molecular of its kind to be prepared for the group 6 transition elements.

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作者
Chisholm, M. H.; Folting, K.; Huffman, J. C.; Kirkpatrick, C. C.; Ratermann, A.;
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年度 1980
页码 p.1-10
总页数 10
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Reaction kinetics; Chemical bonds; Cleavage; Aryl radicals; Molecule molecule interactions; Azides; Molecular structure; Oxygen; Molybdenum compounds; Ligands; Electron acceptors; Yield; Addition reactions; Carbon monoxide; Transition elements;

机译：反应动力学;化学键;裂解;芳基;分子分子相互作用;叠氮化物;分子结构;氧;钼化合物;配体;电子受体;产率;加成反应;一氧化碳;过渡元素;

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专利

1. Facile intermolecular aryl-F bond cleavage in the presence of aryl C-H bonds: Is the eta(2)-arene intermediate bypassed? [J] . Liu WJ, Welch K, Trindle CO, Organometallics . 2007,第10期

机译：在存在芳基C-H键的情况下容易进行分子间芳基-F键裂解：是否绕过eta（2）-芳烃中间体？
2. Iron(Ⅱ) Bromide-Catalyzed Intramolecular C-H Bond Amination [1,2]-Shift Tandem Reactions of Aryl Azides [J] . Quyen Nguyen, Tuyen Nguyen, Tom G. Driver Journal of the American Chemical Society . 2013,第2期

机译：溴化铁催化的分子内C-H键胺化[1,2]-芳基叠氮化物的串联反应
3. Rh_2(ll)-Catalyzed Intramolecular Aliphatic C-H Bond Amination Reactions Using Aryl Azides as the N-Atom Source [J] . Quyen Nguyen, Ke Sun, Tom G. Driver Journal of the American Chemical Society . 2012,第17期

机译：Rh_2（II）催化的芳基叠氮化物作为N原子源的分子内脂肪C-H键胺化反应
4. A Ruthenium-Catalyzed Coupling Reaction of Aryl Ethers with Organoboron Compounds via Carbon-Oxygen Bond Cleavage [C] . Satoshi Ueno, Fumitoshi Kakiuchi, Mayumi Usui, Symposium on Organometallic Chemistry . 2004

机译：通过碳 - 氧粘合裂解芳基醚芳基醚化合物的芳基醚催化烯烃催化反应
5. Transition Metal-Catalyzed Intramolecular Nitrogen-Atom Transfer Reactions of Aryl- and Vinyl Azides [D] . Stokes, Benjamin J. 2011

机译：过渡金属催化的芳基和乙烯基叠氮化物的分子内氮原子转移反应
6. Iron(II) Bromide-Catalyzed Intramolecular C–H Bond Amination–12-shift Tandem Reactions of Aryl Azides [O] . Quyen Nguyen, Tuyen Nguyen, Tom G. Driver -1

机译：铁（II）溴化物的催化分子内C-H键amination- 12芳基叠氮化的-shift串联反应
7. Facile Intermolecular Aryl-F Bond Cleavage in the Presence of Aryl C-H Bonds: Is the h2-Arene Intermediate Bypassed? [O] . -1

机译：在芳基C-H键存在下，体分子间芳基-F粘结裂解：是H 2-芳烃中间体绕过？

Facile Cleavage of the Mo=Mo Bond in Reactions between (Mo2(OBut)6 and Aryl Azides and Molecular Oxygen

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