首页> 美国政府科技报告 >Trapping of Silylenes by 9,10-Dimethylanthracene: 2,3,5,6-Dibenzo-7-Silabicyclo 2.2.1 Hepta-2,5 Dienes

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Trapping of Silylenes by 9,10-Dimethylanthracene: 2,3,5,6-Dibenzo-7-Silabicyclo 2.2.1 Hepta-2,5 Dienes

机译：用9,10-二甲基蒽捕获甲硅烷基：2,3,5,6-二苯并-7-硅杂双环[2.2.1] Hepta-2,5二烯

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Silylenes generated thermally from 7-silanorbornadienes la-c react with 9, 10-dimethylanthracene (DMA) to give 7-silabicyclo hepta-2, 5-dienes 3a-c. For dimethylsilylene, a small amount of 2,3:5,6-dibenzo-1,4,7,7,8,8-hexamethyl-7,8-disilabicyclo octa-2,5-diene is also obtained, arising via Diels-Alder reaction of tetramethyldisilene with MDA. Keywords: Dienes, Silanes, Methyl radicals.

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Sekiguchi, A.; West, R.;
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年度 1986
页码 p.1-4
总页数 4
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Dienes; Silanes; Anthracenes; Response; Methyl radicals; Reprints;

机译：二烯;硅烷;蒽;响应;甲基;重印;

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1. 7-Isopropylidene-N2,N3,N5,N6-tetramethoxy-N2,N3,N5,N6-tetramethylbicyclo[2.2.1]hepta-2,5-diene-2,3,5,6-tetracarboxamide [J] . Herges R., N#228, ther C., Acta Crystallographica Section E: Crystallographic Communications . 2014,第4期

机译：7-异亚丙基-N2，N3，N5，N6-四甲氧基-N2，N3，N5，N6-四甲基双环[2.2.1]庚-2,5-二烯-2,3,5,6-四甲酰胺
2. 7-Isopropylidene-N2,N3,N5,N6-tetramethoxy-N2,N3,N5,N6-tetramethylbicyclo[2.2.1]hepta-2,5-diene-2,3,5,6-tetracarboxamide [J] . Herges R., N#228, ther C., Acta Crystallographica Section E: Crystallographic Communications . 2014,第4期

机译：7-异亚丙基-N2，N3，N5，N6-四甲氧基-N2，N3，N5，N6-四甲基双环[2.2.1]庚-2,5-二烯-2,3,5,6-四甲酰胺
3. Crystal structure of [(2,3,5,6-)-bicyclo[2.2.1]hepta-2,5-diene]diiodoplatinum(II), PtI_2(C_7H_8) [J] . Kwang Ha Zeitschrift fur Kristallographie. New crystal structures . 2010,第2期

机译：[（2,3,5,6-）-双环[2.2.1]庚-2,5-二烯]二碘铂（II），PtI_2（C_7H_8）的晶体结构
4. A comparison of the reactivities of CCO radicals and free carbon atoms with bicyclo[2.2.1]hepta-2,5-diene and the photochemical reactions of allene with alkenes [D] . Wu, Haitao. 2001

机译：双环[2.2.1]庚-2,5-二烯与CCO自由基和游离碳原子的反应性比较以及烯与烯烃的光化学反应
5. 7-Isopropylidene-N2N3N5N6-tetramethoxy-N2N3N5N6-tetramethylbicyclo2.2.1hepta-25-diene-2356-tetracarboxamide [O] . Benjamin Sahlmann, Christian Näther, Rainer Herges 2014

机译：7-异丙基亚烷基-N2N3N5N6-四甲基氧基-N2N3N5N6-四甲基二环2.2.1庚-25-二烯-2356-四羧酰胺
6. 7-Isopropylidene-N2,N3,N5,N6-tetramethoxy-N2,N3,N5,N6-tetramethylbicyclo[2.2.1]hepta-2,5-diene-2,3,5,6-tetracarboxamide [O] . Benjamin Sahlmann, Christian Näther, Rainer Herges 2014

机译：7-异亚丙基-N 2，N 3，N 5，N 6 - 四甲氧基-N 2，N 3，N 5，N 6 - 四甲基双环[2.2.1]庚-2,5-二烯-2,3,5,6-四甲酰胺
7. Heptacyclo(5.5.1.14,10.02,6.03,11.05,9.08,12)tetradecane-13,14- bis(spiro-1 prime-cyclopentane): A New C22H28 Nonacyclic Cage Hydrocarbon. Improved Synthesis Bicyclo(2.2.1)hepta-2,5-diene-7-spiro-1 prime-cyclo-pentane [R] . Marchand, A. P., Wu, A. H. 1985

机译：Heptacyclo（5.5.1.14,10.02,6.03,11.05,9.08,12）十四烷-13,14-双（螺-1-环戊烷）：新的C22H28非环状笼烃。改进的合成双环（2.2.1）七-2,5-二烯-7-螺-1-原 - 环 - 戊烷

Trapping of Silylenes by 9,10-Dimethylanthracene: 2,3,5,6-Dibenzo-7-Silabicyclo 2.2.1 Hepta-2,5 Dienes

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