Valence band structure of the NiAl—Mo alloy from thephotoelectron spectrum

摘要

The valence band structures of the NiAl–Mo alloy was investigated by photoelectron spectroscopy. The valence band spectra of the NiAl–Mo alloy was shifted away from the Fermi level so that the Ni-d-band centroid moved to a higher energy by 0.22 eV as Mo was added. A possible explanation lied in the overlap of Ni-d bands in the energy with Mo-d and Al-p bands. The participation of Mo-d bands was correlated with the site preference of Mo in NiA1 alloys.