Synthesis of 1,2-Epoxycyclopentane and/or 1,2-Cyclopentanediol by Oxidation of Cyclopentene with Aqueous Solution of Hydrogen Peroxide

L. V. Melnik; A. E. Meshechkina; G. V. Rybina

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Synthesis of 1,2-Epoxycyclopentane and/or 1,2-Cyclopentanediol by Oxidation of Cyclopentene with Aqueous Solution of Hydrogen Peroxide

机译：过氧化氢水溶液氧化环戊烯合成1，2-环氧环戊烷和/或1，2-环戊二醇

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摘要

A method for synthesizing 1,2-epoxycyclopentane and 1,2-cyclopentanediol by oxidation of cyclopentene with an aqueous hydrogen peroxide solution in a two-phase system has been developed. A universal flow chart of the directed synthesis of the products is presented.

机译：已经开发了在两相系统中通过用过氧化氢水溶液氧化环戊烯来合成1，2-环氧环戊烷和1，2-环戊二醇的方法。给出了产物定向合成的通用流程图。

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《Petroleum Chemistry》 |2012年第5期|共5页
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L. V. Melnik; A. E. Meshechkina; G. V. Rybina;
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中图分类石油化学工业;
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1. Synthesis of 1,2-Epoxycyclopentane and/or 1,2-Cyclopentanediol by Oxidation of Cyclopentene with Aqueous Solution of Hydrogen Peroxide [J] . L. V. Melnik, A. E. Meshechkina, G. V. Rybina Petroleum Chemistry . 2012,第5期

机译：过氧化氢水溶液氧化环戊烯合成1，2-环氧环戊烷和/或1，2-环戊二醇
2. New green catalytic manufacture of glutaric acid from the oxidation of cyclopentane-1,2-diol with aqueous hydrogen peroxide [J] . Hui Chen, Wei-Lin Dai, Ruihua Gao Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications . 2007,第2期

机译：环戊烷-1,2-二醇与过氧化氢水溶液的氧化反应合成戊二酸的新绿色催化方法
3. 1,2-oxazines as building blocks for stereoselective synthesis: Preparation of oxygen-substituted 1,2-oxazines, either by alcohol addition or by epoxidation, and subsequent hydrogenation leading to 1,2-amino alcohols and pyrrolidines [J] . Zimmer R., Buchholz M., Collas M., European journal of organic chemistry . 2010,第21期

机译：1,2-恶嗪作为立体选择性合成的基础：通过醇加成或环氧化制备氧取代的1,2-恶嗪，然后氢化生成1,2-氨基醇和吡咯烷
4. Studies on the destruction of some aqueous solutions of organic azo dyes (Brown Vopsider DMG 218) by oxidation with hydrogen peroxide associated with UV irradiation [C] . Mioara Sorpateanu, Carmen Zabaria 12th Romanian International Conference on Chemistry and Chemical Engineering, Sep 13-15, 2001, Bucharest, Romania . 2001

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5. THE SYNTHESIS AND CHEMISTRY OF A REMOTELY FUNCTIONALIZED UNSYMMETRICALLY SUBSTITUTED 1,2-DIOXANE (PHEROMONES, TIN-HYDRIDE, PEROXIDES, SINGLET OXYGEN, HYDROGENATION). [D] . SIDENSTICK, JOHN EDWARD. 1985

机译：远程官能化的不对称取代的1,2-二恶烷（信息素，氢化锡，过氧化物，单氧，加氢）的合成与化学。
6. Electrolytic control of hydrogen peroxide release from calcium peroxide in aqueous solution [O] . Yunfei Xue, Ljiljana Rajic, Long Chen, -1

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7. Autocatalytic photodegradation of Ru(ii)(2,2′-bipyridine)2DAD+ (DADH = 1,2-dihydroxyanthracene-9,10-dione) by hydrogen peroxide under acidic aqueous conditions [O] . Lingli Zeng, Dumitru Sirbu, Nikolai V. Tkachenko, 2021

机译：在酸性含水条件下，过氧化氢Ru（II）（2,2'-二吡啶）2dad +（Dadh = 1,2-二羟基蒽蒽-9,10-二酮）的自催化光降解
8. Abiotic Dehalogenation of 1,2-Dichloroethane and 1,2-Dibromoethane in Aqueous Solution Containing Hydrogen Sulfide [R] . Barbash, J. E., Reinhard, M. 1989

机译：含硫化氢水溶液中1,2-二氯乙烷和1,2-二溴乙烷的非生物脱卤

Synthesis of 1,2-Epoxycyclopentane and/or 1,2-Cyclopentanediol by Oxidation of Cyclopentene with Aqueous Solution of Hydrogen Peroxide

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