1,3-dibromo-5,5-dimethylhydantoin [DBDMH] as an efficient and selective agent for the oxidation of thiols to disulfides in solution or under solvent-free conditions

Khazaei A; Zolfigol MA; Rostami A

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1,3-dibromo-5,5-dimethylhydantoin [DBDMH] as an efficient and selective agent for the oxidation of thiols to disulfides in solution or under solvent-free conditions

机译：1,3-二溴-5,5-二甲基乙内酰脲[DBDMH]作为溶液中或无溶剂条件下硫醇氧化为二硫化物的有效和选择性试剂

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摘要

A useful method for oxidation of various thiols to their corresponding disulfides with 1,3-dibromo-5,5-dimethylhydantoin (DBDMH) in very short reaction times and mild conditions under both solution and solvent-free conditions is described.

机译：描述了一种有用的方法，可在非常短的反应时间和温和条件下，在无溶液和无溶剂条件下，用1,3-二溴-5,5-二甲基乙内酰脲（DBDMH）将各种硫醇氧化为相应的二硫化物。

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《Synthesis: International Journal of Methods in Synthetic Organic Chemistry》 |2004年第18期|共3页
作者
Khazaei A; Zolfigol MA; Rostami A;
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正文语种 eng
中图分类有机化学;
关键词
1; 3-dibromo-5; 5-dimethylhydantoin; oxidation; thiol; disulfide; HETEROGENEOUS SYSTEM; SILICA-GEL; MILD; THIONITRITES; REAGENT; CHLOROCHROMATE; CONVENIENT; ALCOHOLS; BROMINE;

机译：1;3-二溴-5;5-二甲基乙内酰脲;氧化;硫醇;二硫化物;异相体系;硅胶-凝胶;混溶;亚硫酸盐;试剂;氯代铬酸盐;方便;醇;溴;

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1. 1,3-dibromo-5,5-dimethylhydantoin [DBDMH] as an efficient and selective agent for the oxidation of thiols to disulfides in solution or under solvent-free conditions [J] . Khazaei A, Zolfigol MA, Rostami A Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2004,第18期

机译：1,3-二溴-5,5-二甲基乙内酰脲[DBDMH]作为溶液中或无溶剂条件下硫醇氧化为二硫化物的有效和选择性试剂
2. 1,3-Dibromo-5,5-dimethylhydantoin (DBH)/kaolin: An efficient reagent system for the synthesis of 14-aryl-14H-dibenzoa,jxanthenes under solvent-free conditions [J] . Farhad Shirini, Nader Ghaffari Khaligh, Gholam Hossein Imanzadeh, 中国化学快报（英文版） . 2012,第010期

机译：1,3-二溴-5,5-二甲基乙内酰脲（DBH）/高岭土：一种无溶剂条件下合成14-芳基-14H-二苯并a，j黄嘌呤的有效试剂体系
3. 1,3-Dibromo-5,5-dimethylhydantoin （DBH）/kaolin： An efficient reagent system for the synthesis of 14-aryl-14H- dibenzoajxanthenes under solvent-free conditions [J] . Farhad Shirini, Nader Ghaffari Khaligh, Gholam Hossein Imanzadeh, 中国化学快报：英文版 . 2012,第010期

机译：1,3-二溴-5,5-二甲基乙内酰脲（DBH）/高岭土：无溶剂条件下合成14-芳基-14H-二苯并aj黄嘌呤的有效试剂体系
4. TBN/DBDMH Catalyst: Nonmetal-driven Approach to Highly Efficient and Selective Aerobic Oxidation of Sulfides to Sufoxides by Oxygen [C] . The 12th Asian Pacific Confederation of Chemical Engineering Congress(第十二届亚太化工联盟大会暨化工展览会)论文集 . 2008

机译：TBN / DBDMH催化剂：非金属驱动的方法，通过氧气将硫化物高效，选择性地好氧氧化为亚砜。
5. The cell surface reductive function of mammalian cells and its inhibition by agents that interfere with thiol:disulfide interchange. [D] . Rivera, Alicia. 1997

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1,3-dibromo-5,5-dimethylhydantoin [DBDMH] as an efficient and selective agent for the oxidation of thiols to disulfides in solution or under solvent-free conditions

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