Study on synthesis and anticorrosion properties of polymer nanocomposites based on super paramagnetic Fe_2O_3-NiO nanoparticle and polyaniline

摘要

In this study, Fe_2O_3NiO/PANi nanocomposites were prepared and their anticorrosion properties were investigated. The Fe_2O_3NiO nanoparticles were synthesized by precipitation-oxidation methods. Fe_2O_3-NiO-PANi nanocomposites were prepared by in situ polymerization of aniline monomer in the presence of Fe_2O_3NiO nanoparticle. The structure of the polymer nanocomposite was characterized by SEM and X-ray method. The electrical conductivity, magnetic properties and anticorrosion properties of the materials were examined by the conventional four probe method, vibrating magnetometer and by impedance measurement method. The results show that the Fe_2O_3NiO nanoparticles have the uniform size with the size ranging from 50 to 60 ran. By the formation of polymer nanocomposite, the Fe_2O_3 ? NiO phase is well dispersed in the PANi polymer matrix. But the Fe_2O_3NiO nanoparticles are not exfoliated from its agglomerate structure. The polymer nanocomposite showed both magnetic and conductive properties. With increasing Fe_2O_3NiO content, both the saturated magnetization and the coercive force increase and reach the value of 0.31 emu/g and 162.56 Oe by the Fe_2O_3NiO content of 5%, respectively. In contrast, the electrical conductivity of the polymer nanocomposite decreases with increasing Fe_2O_3NiO content from 0.353 S/cm of neat PANi to 0.075 S/cm by the Fe_2O_3NiO content of 5%. From the anticorrosion investigation, it was revealed that the protective performance of polyurethane paint containing Fe_2O_3NiO/PANi nanocomposite was significantly improved with increasing Fe_2O_3NiO/PANi content.