Allyltriphenylphosphonium peroxodisulfate (CH_2=CHCH_2PPh_3)_2S_2O_8:an efficient and convenient reagent for the oxidation of alcohols and silyl and THP-ethers under nonaqueous conditions

摘要

The preparation of allyltriphenylphosphonium peroxodisulfate (ATPPD) as a new and efficient reagent for the oxidation of primary and secondary alcohols,trimethylsilyl and tetrahydropyranyl (THP) ethers to their corresponding carbonyl compounds in refluxing acetonitrile with 1.1:1 molar equivalents of the oxidant is described.