Synthesis of Spirooxindolo/Spiroindano Nitro Pyrrolidines through Regioselective Azomethine Ylide Cycloaddition Reaction

Mahalingam Poornachandran; Ragavachary Raghunathan

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Synthesis of Spirooxindolo/Spiroindano Nitro Pyrrolidines through Regioselective Azomethine Ylide Cycloaddition Reaction

机译：区域选择性偶氮甲啶叶立德环加成反应合成吡咯并吲哚/螺吡喃多硝基吡咯烷

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摘要

Synthesis of a series of spirooxindolonitro pyrrolizidines and spiroindanoni-tro pyrrolizidines has been accomplished.The nonstabilized azomethine ylides generated from isatin and ninhydrin with proline reacted with nitro styrenes to regio-selectively yield spirocycloadducts.

机译：已经完成了一系列螺杂吲哚并硝基吡咯并核苷的合成。由靛红和茚三酮与脯氨酸生成的不稳定的偶氮甲酰亚胺与硝基苯乙烯反应生成区域选择性的螺环加合物。

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《Synthetic Communications》 |2007年第15期|共11页
作者
Mahalingam Poornachandran; Ragavachary Raghunathan;
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正文语种 eng
中图分类有机化学;
关键词
azomethine; cycloaddition; oxindole; pyrrolizidine; ylide;

机译：偶氮甲碱环加成羟吲哚吡咯并核苷内酯;

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1. Synthesis of Spirooxindolo/Spiroindano Nitro Pyrrolidines through Regioselective Azomethine Ylide Cycloaddition Reaction [J] . Mahalingam Poornachandran, Ragavachary Raghunathan Synthetic Communications . 2007,第13a15期

机译：区域选择性偶氮甲啶叶立德环加成反应合成吡咯并吲哚/螺吡喃多硝基吡咯烷
2. Regioselective synthesis of novel spirooxindolo and spiroindano nitro pyrrolidines through 3+2 cycloaddition reaction [J] . Poornachandran M, Muruganantham R, Raghunathan R Synthetic Communications . 2006,第2期

机译：通过3 + 2环加成反应区域反应合成新型螺氧基辛多洛和螺吲哚基硝基吡咯烷
3. Regioselective Synthesis of Novel Spirooxindolo and Spiroindano Nitro Pyrrolidines Through 3+2 Cycloaddition Reaction [J] . Mahalingam Poornachandran, Rajendran Muruganantham, Ragavachary Raghunathan Synthetic Communications . 2006,第1期

机译：通过3 + 2环加成反应区域合成新型螺氧基辛多洛和螺吲哚诺硝基吡咯烷
4. A facial regioselective synthesis of novel pyrrolizidines through azomethine ylide cycloaddition reaction [C] . Yaghoub Sarrafi, Kamal Alimohammadi European Symposium on Organic Chemistry . 2009

机译：通过氮杂甲酸钠环加入反应进行新型吡咯烷的面部区域选择性合成
5. I. Completion of the synthesis of Kopsia lapidilecta alkaloid (+/-)-lapidilectine B. II. Synthesis of 1-azabicyclo[n.3.0]alkanes via [3+2] cycloadditions of nonstabilized azomethine ylides [D] . Stoy, Patrick 2004

机译：I.完成了Kopsia lapidilecta生物碱（+/-）-lapidilectine的合成B. II。通过不稳定的偶氮甲亚胺的[3 + 2]环加成反应合成1-氮杂双环[n.3.0]烷烃
6. A Novel One-Pot Green Synthesis of Dispirooxindolo-pyrrolidines via13-Dipolar Cycloaddition Reactions of Azomethine Ylides [O] . Abdulrahman I. Almansour, Natarajan Arumugam, Raju Suresh Kumar, 2015

机译：通过偶氮甲Y叶立德的13-偶极环加成反应合成新颖的一锅绿色双螺并吡咯并吡咯烷类化合物
7. Highly diastereoselective 1,3-dipolar cycloaddition of nonstabilized azomethine ylides to 3-nitro-2-trihalomethyl-2H-chromenes: Synthesis of 1-benzopyrano[3,4-c]pyrrolidines [O] . Korotaev, V. Y., Barkov, A. Y., Moshkin, V. S., 2013

机译：非稳定的甲亚胺烷基化物对3-硝基-2-三卤甲基-2H-色烯的高度非对映选择性1,3-偶极环加成反应：1-苯并吡喃并[3,4-c]吡咯烷的合成

Synthesis of Spirooxindolo/Spiroindano Nitro Pyrrolidines through Regioselective Azomethine Ylide Cycloaddition Reaction

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