Hydrothermal syntheses and crystal structures of two Cu~I coordination polymers:[Cu~I(TATP)(CN)]_n and[Cu~I(bpy)(SCN)]_n(TATP=1,4,8,9-tetranitrogen-trisphene,bpy=2,2'-bipyridine)

摘要

Two new Cu~I coordination polymers,[Cu~I(TATP)(CN)]_n(1)and[Cu~I(bpy)(SCN)]_n(2)(TATP=1,4,8,9-tetranitrogen-trisphene,bpy=2,2'-bipyiridine),have been synthesized under hydrothermal conditions and structurally characterized by elemental analysis,IR,and X-ray crystallography.In 1 and 2,the metal centers are linked by bridging CN~-/SCN~-to form one-dimensional chains in the crystals and are stabilized by interchain pi-PI stacking interaction.