Spectroscopic and thermodynamic study of charge transfer interactions of retinol palmitate with [60]- and [70]fullerenes by absorption spectrometric method

摘要

Retinol palmitate (1). which is commonly called 'Vitamin A palmitate', has been shown to form charge transfer (CT) complexes with a series of electron acceptors including [60]- and [70]fullerenes, and from the trends in CT transition energies the vertical ionization potential of 1 has been estimated to be 7.73 eV. Stoichiometries of the fullerene complexes have been shown to be 1(Vitamin 1): ([70]fullerene) and 1(Vitamin 1): 2([60]fullerene). The enthalpies and entropies of formation of these two complexes have been determined by estimating the formation constants spectrophotometrically at five different temperatures. The complexation phenomenon may be utilised to dissolve the fullerenes in the non-toxic Vitamin A oil and the solution may be used for testing the biological activity of the fullerenes in vivo. (c) 2004 Elsevier B.V. All rights reserved.