METHOD FOR PRODUCING C60 and C70 fullerenes and reactor for the production of soot containing fullerenes

摘要

1.method u043fu043eu043bu0443u0447u0435u043du0438u00a0 u0444u0443u043bu043bu0435u0440u0435u043du043eu0432 u044160 and u044170, u0445u0430u0440u0430u043au0442u0435u0440u0438u0437u0443u044eu0449u0438u0439u0441u00a0, lead accumulation u0444u0443u043bu043bu0435u0440u0435u043du0441u043eu0434u0435u0440u0436u0430u0449u0435u0439 soot obtained u044du043bu0435u043au0442u0440u043eu0434u0443u0433u043eu0432u044bu043c method in u043au043eu043du0432u0435u043au0446u0438u043eu043du043du043eu043c bec ke an inert gas in a reactor u0433u0435u043bu0438u00a0 closed type, and further derive and u044du043au0441u0442u0440u0430u0433u0438u0440u0443u044eu0442 in the u0441u043eu043au0441u043bu0435u0442u0430 aromatic solvent u0442u043eu043bu0443u043eu043bu043eu043c, extract with u0441u043eu0434u0435 whinny u0444u0443u043bu043bu0435u0440u0435u043du0430 u044160 to 95% u043eu0441u0430u0436u0434u0430u0435u0442u0441u00a0 from solutionu043eu0431u043eu0433u0430u0449u0430u00a0 solution over u043eu0441u0430u0434u043au043eu043c u0444u0443u043bu043bu0435u0440u0435u043du043eu043c u044170 to 70%, then u044160 fullerenes and u044170 independently u0440u0430u0437u0434u0435u043bu00a0u044eu0442 to chromatography based columns using a u043du0435u043fu043eu0434u0432u0438 u0436u043du043eu0439 phase wood activated coal, mobile phase, toluene or chlorobenzene, the target product u043au0440u0438u0441u0442u0430u043bu043bu0438u0437u0443u044eu0442.;2. method for 1, the target product, if necessary, subjected to further treatment u043fu0435u0440u0435u043au0440u0438u0441u0442u0430u043bu043bu0438u0437u0430u0446u0438u0435u0439 or sublimation in a vacuum.;3.the reactor u0434u043bu00a0 u043fu043eu043bu0443u0447u0435u043du0438u00a0 u0444u0443u043bu043bu0435u0440u0435u043du0441u043eu0434u0435u0440u0436u0430u0449u0435u0439 soot containing u043eu0445u043bu0430u0436u0434u0430u0435u043cu0443u044e sealed chamber filled with an inert gas, which contains two electrodes, the aimed at the u0430u043du043eu0434u043du043eu043c and u043au0430u0442u043eu0434u043du043eu043c u0442u043eu043au043eu0432u0432u043eu0434u0430u0445, connected to an electric block u043fu0438u0442u0430u043du0438u00a0, the electrode u0430u043du043eu0434u043du043eu0433u043e u0442u043eu043au043eu0432u0432u043eu0434u0430 u00a0u0432u043bu00a0u0435u0442u0441u00a0 still the u0441u0436 u0438u0433u0430u0435u043cu044bu0439 u0433u0440u0430u0444u0438u0442u043eu0432u044bu0439 rodcathodic electrode u0442u043eu043au043eu0432u0432u043eu0434u0430 u00a0u0432u043bu00a0u0435u0442u0441u00a0 u0433u0440u0430u0444u0438u0442u043eu0432u044bu0439 tip mounted with the possibility of u043fu0435u0440u0435u043cu0435u0449u0435u043du0438u00a0 and u0440u0435u0433u0443u043bu0438u0440u043eu0432u0430u043du0438u00a0 u0440u0430u0441u0441u0442u043eu00a0u043du0438u00a0 between electrodes with images u0430u043du0438u0435u043c u0440u0430u0437u0440u00a0u0434u043du043eu0433u043e interval between them, and the device u0432u0430u043au0443u0443u043cu0438u0440u043eu0432u0430u043du0438u00a0 and an inert gas, the u0433u0430u0437u043eu0432u0432u043eu0434u0430u043cu0438 camera u043eu0442u043bu0438u0447u0430u044eu0449u0438u0439u0441u00a0, u0442u043eu043au043eu0432u0432u043eu0434u044b with electrodes mounted on opposite sides of the chamber.u0441u043eu043eu0441u043du043e each other, and the electrodes are in the coaxial hollow body with open u0442u043eu0440u0446u0430u043cu0438 them within the cell, with the possibility of rotation and its continued installation steel u043fu0435u0440u043fu0435u043du0434u0438u043au0443u043bu00a0u0440u043du043e axis along the axis of the axis of the electrodes and the upper and lower flanges, is installed on the chamber, with the upper flange is available a axis with u043fu043eu0440u0448u043du0435u043c at the end, with the possibility of longitudinal u043fu0435u0440u0435u043cu0435u0449u0435u043du0438u00a0,placed inside the shell, and the lower flange is connected to the storage device soot.;4. reactor for 3, u043eu0442u043bu0438u0447u0430u044eu0449u0438u0439u0441u00a0, characterised by a hard anodic u0442u043eu043au043eu0432u0432u043eu0434 performed with the possibility of replacing the electrode rods of bootloader, co located with the camera.