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CERAMIC FOAM PROCESSING BY THE CHEMICAL VAPOR INFILTRATION OF A GRAPHITE FELT WITH SIC FOR CERAMIC COMPOSITE APPLICATIONS

机译:用于陶瓷复合材料的石墨毡的化学气相渗碳石墨毡的陶瓷泡沫加工

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摘要

This investigation focuses on the fabrication of fibrous silicon carbide (SiC) ceramic foams by the Chemical Vapor Infiltration (CVI) of SiC into a low cost graphite felt. Selected foams were then oxidized to produce foams consisting of hollow SiC fibers. Depending on infiltration time, densities from 0.3 to 1.0 g/cm{sup}3 were obtained (0.268 to 0.925 g/cm{sup}3 after oxidation). Compressive strength data (pre and post oxidized foams) and flexural strength data (post oxidized foams) are presented as a function of density. This unique ceramic foam with high temperature capabilities and reasonable compressive and flexural strengths was also used as a light weight core in the development of a sandwich composite structure. Coated Nicalon 4-ply laminates were used as faceplates. The composite processing included both Polymer Impregnation Pyrolysis (PIP) and the CVI of the final laminate-foam structure with a SiC overcoat. Overall composite flexural strengths are reported with respect to the bulk density of the foam core and the composite. Relatively small, 1.5 × 10 × 0.5 cm, sandwich type composites were successfully produced and possibly represent a lightweight structure for high temperature (>1000℃) applications.
机译:这项研究的重点是通过将SiC化学气相渗透(CVI)渗透到低成本石墨毡中来制造纤维状碳化硅(SiC)陶瓷泡沫。然后将选定的泡沫氧化以产生由中空SiC纤维组成的泡沫。根据渗透时间,获得0.3至1.0g / cm 3的密度(氧化后为0.268至0.925g / cm 3)。压缩强度数据(氧化前后的泡沫)和抗弯强度数据(氧化后的泡沫)是密度的函数。这种独特的陶瓷泡沫具有高温性能以及合理的抗压强度和抗弯强度,在开发三明治复合结构时也被用作轻质芯材。涂覆的Nicalon 4层层压板用作面板。复合工艺包括聚合物浸渍热解(PIP)和带有SiC外涂层的最终层压泡沫结构的CVI。据报总的复合材料抗弯强度与泡沫芯和复合材料的堆积密度有关。已经成功生产了尺寸相对较小的1.5×10×0.5 cm夹心型复合材料,可能代表了轻型结构,适用于高温(> 1000℃)应用。

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