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Time Domain Reflectometry developments in soil science: III. Small-scale probe for measuring bulk soil electrical conductivity

机译:时域反射法在土壤科学中的发展:III。小型探针,用于测量土壤的电导率

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It is commonly believed that Time Domain Reflectometry (TDR) measures bulk soil electrical conductivity (EC) and volumetric water content within the same, well-defined sample volume. However, recent studies have shown that the sample volume is a function of the distribution of EC and dielectric permittivity near the probe. One result of this spatially distributed sensitivity is measurement-induced dispersion. That is, when TDR is used to measure a sharp advancing solute front, the measured EC is some average across the sharp front, leading to incorrect smoothing of the breakthrough curve. A reduction of the probe dimensions is the only solution to this artificial smoothing problem. In this study, a small scale TDR probe is presented and tested. The small probe dimensions produce a near point measurement of EC but make water content measurements unreliable. The small scale EC TDR (SEC-TDR) probe is simple, inexpensive, and made with readily available components. A solute transport experiment was carried out under saturated conditions in a plastic pipe packed with coarse silica sand. Five SEC-TDR probes were inserted, monitoring the EC at various positions along the column, and a coaxial flow cell was used to monitor the effluent EC. Step solute breakthrough and displacement breakthrough responses were created using tap water and a KCl solution. Highly detailed measurements of EC were obtained from which the dispersivity (lambda) was inferred. The lambda measured by the SEC-TDR probes was significantly lower than lambda measured in the effluent by the coaxial flow cell, suggesting that the SEC-TDR probe can reduce the problem of TDR-induced dispersion under even the most challenging conditions.
机译:通常认为,时域反射法(TDR)可在相同且定义明确的样品体积内测量整体土壤电导率(EC)和体积含水量。但是,最近的研究表明,样品体积是探针附近EC和介电常数的分布的函数。这种空间分布的灵敏度的结果是测量引起的色散。也就是说,当使用TDR来测量尖锐的前进溶质峰时,测得的EC为整个尖峰前的平均值,从而导致穿透曲线的平滑化不正确。减小探头尺寸是解决这种人工平滑问题的唯一方法。在这项研究中,提出并测试了小型TDR探针。小探头尺寸可产生EC的近点测量值,但含水量测量值不可靠。小型EC TDR(SEC-TDR)探针简单,便宜,并且使用容易获得的组件制成。在充满粗硅砂的塑料管中,在饱和条件下进行溶质迁移实验。插入了五个SEC-TDR探针,以监测沿色谱柱不同位置的EC,并使用同轴流通池监测流出的EC。使用自来水和KCl溶液创建了步骤溶质突破和位移突破响应。获得了高度详细的EC测量值,从中可以推断出分散度(λ)。通过SEC-TDR探针测得的λ值显着低于通过同轴流通池在流出物中测得的λ值,这表明SEC-TDR探针即使在最具挑战性的条件下也可以减少TDR诱导的分散问题。

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