Calcium doped ceria-based materials for cost-effective intermediate temperature solid oxide fuel cells

摘要

This paper studies preparation and characterization of the calcium doping ceria (CCO) and carbonate composite materials. The material preparation was performed based on an oxalate co-precipitation. Various material characterizations were carried on the material phase structure based on XRD, TG/DSC and their fuel cell applications. The CCO materials showed a two-phase composite with very high ionic conductivity, 0.01 to 0.5 S cm~(-1) between 400 and 700 ℃. Using the CCO-composites as the electrolytes for intermediate temperature solid oxide fuel cells (ITSOFC) a high performance, e.g., 600 mW cm~(-2) was demonstrated at 600 ℃.