Microwave absorption enhancement of multifunctional composite microspheres with spinel Fe _3O _4 cores and anatase TiO _2 shells

摘要

Multifunctional composite microspheres with spinel Fe _3O _4 cores and anatase TiO _2 shells (Fe _3O _4@TiO _2) are synthesized by combining a solvothermal reaction and calcination process. The size, morphology, microstructure, phase purity, and magnetic properties are characterized by scanning electron microscopy, transmission electron microscopy (TEM), high-resolution TEM, selected-area electron diffraction, electron energy loss spectroscopy, powder X-ray diffraction, and superconducting quantum interference device magnetometry. The results show that the as-synthesized microspheres have a unique morphology, uniform size, good crystallinity, favorable superparamagnetism, and high magnetization. By varying the experimental conditions such as Fe _3O _4 size and concentration, microspheres with different core sizes and shell thickneses can be readily synthesized. Furthermore, the microwave absorption properties of these microspheres are investigated in terms of complex permittivity and permeability. By integration of the chemical composition and unique structure, the Fe _3O _4@TiO _2 microspheres possess lower reflection loss and a wider absorption frequency range than pure Fe _3O _4. Moreover, the electromagnetic data demonstrate that Fe _3O _4@TiO _2 microspheres with thicker TiO _2 shells exhibit significantly enhanced microwave absorption properties compared to those with thinner TiO _2 shells, which may result from effective complementarities between dielectric loss and magnetic loss. All the results indicate that these Fe _3O _4@TiO _2 microspheres may be attractive candidate materials for microwave absorption applications. Microspheres with spinel Fe _3O _4 cores and anatase TiO _2 shells are synthesized with different core sizes and shell thickneses. The as-synthesized microspheres have a unique morphology, uniform size, good crystallinity, favorable superparamagnetism, and high magnetization. The Fe _3O _4@TiO _2 microspheres possess lower reflection loss and wider absorption frequency range than pure Fe _3O _4.