Recovery of zinc from spent pickling solutions using an electrochemical reactor in presence and absence of an anion-exchange membrane: Galvanostatic operation

摘要

The performance of a one- and two-compartment electrochemical reactor under galvanostatic control for zinc recovery present in the spent pickling solutions is studied in this paper. These solutions, which mainly contain ZnCl2 and FeCl2 in aqueous HCl media, come from the hot dip galvanizing industry. The effect of the anion-exchange membrane (AEM) on the figures of merit of the electrochemical reactor is analyzed. In the absence of iron in solution, as the current value was shifted towards more negative values, the zinc fractional conversion increased because of the increase in the zinc reduction rate. However, the increase in current values made current efficiency decrease due to the hydrogen-reduction side reaction, which caused an increment in the specific energy consumption. The presence of iron in synthetic solutions led to a decrease in current efficiency associated with the reverse redox Fe~(2+)/Fe~(3+) system and to the enhancement of the HER, which also induced increments in the local pH and the subsequent zinc redissolution. These adverse effects related to the presence of iron could be minimized by the interposition of an AEM. In this case, the zinc redissolution was eliminated which enabled zinc conversion values close to 100% together with higher current efficiencies as the consumption of current by the system Fe~(2+)/Fe~(3+) was diminished.