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Organic Materials for Photovoltaic and Light-Emitting Devices

机译:光伏和发光器件的有机材料

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摘要

Materials for organic photovoltaic cells and light-emitting devices are reviewed. Dye-sensitized systems represent the most studied of these materials as they offer high efficiency of photoelectric energy conversion. Systems demonstrating efficient luminescence were identified; they are based on conjugated polymers, complexes of rare-earth elements with organic ligands, and dyes. To achieve efficient photoelectric conversion, different types of sensitizing dyes will be tested. Phthalocyanines and pentacenes are of special interest. Phthalocyanines are the most promising materials: they are easily synthesized and nontoxic, and their electric characteristics are widely investigated. Harnessing the unique electron-acceptor properties of the C_(60) molecule, one can attain considerable enhancement in the efficiency of solar-energy conversion into electricity. Organic photovoltaic cells are often made on the basis of aromatic and heterocyclic polymers-poly(p-phenylene-vinylene), polyanilines, polypyrroles, and polythiophenes. Organic photoconducting materials offer high photosensitivity and low dark current. They are readily available and can be easily deposited on a substrate, which make them suitable for the fabrication of relatively cheap photovoltaic cells.
机译:综述了用于有机光伏电池和发光器件的材料。染料敏化系统代表了对这些材料的最深入研究,因为它们可提供高效率的光电能量转换。确定了展示有效发光的系统;它们基于共轭聚合物,稀土元素与有机配体的复合物以及染料。为了实现有效的光电转换,将测试不同类型的增感染料。酞菁和戊烷特别受关注。酞菁是最有前途的材料:它们易于合成且无毒,其电气特性已得到广泛研究。利用C_(60)分子的独特电子受体特性,可以在太阳能转化为电能的效率上获得相当大的提高。有机光伏电池通常基于芳族和杂环聚合物-聚对苯撑-亚乙烯基,聚苯胺,聚吡咯和聚噻吩制成。有机光电导材料具有高光敏性和低暗电流。它们容易获得并且可以容易地沉积在基底上,这使得它们适合于制造相对便宜的光伏电池。

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