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Petrographic and mid-infrared spectroscopy study of shocked feldspar in the Asuka-881757 Lunar gabbro meteorite sample

机译:Asuka-881757月球辉长岩陨石样品中冲击长石的岩石学和中红外光谱研究

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We investigated three types of shocked feldspar in the Asuka-881757,531-2 sample with mid-infrared spectroscopy (reflectance mode). Under the petrographic microscope three types of site were characterized by (1) undulatory extinction, (2) modulatory extinction with isotropic patches and decreased interference color, and (3) isotropic, lath-shaped feldspars, which is indicative of maskelynite. The IR emissivity maximum (Christiansen feature=CF) changes with the chemical composition of feldspar. One of the Christiansen composition features exhibits a wave length peak of 1234 cm~(-1) for anorthite; another feature appears at 1245 cm~(-1) for maskelynite (Palomba et al. 2006). With the help of IR spectroscopy we observed three vibrational types in our spectra: (1) peaks of depolimerization of SiO_4 tetrahedra (500-650 cm~(-1), 950-1150 cm~(-1)), (2) peaks of stretching and bending vibrational modes of SiO_6 octahedra (750-850 cm~(-1)), and (3) Si-O stretching vibration of SiO_4 units (Johnson and Horz 2003; Johnson et al. 2003, 2007). All these vibration types were observed at the less shocked sites. In the spectrum of highly shocked maskelynite only a broader band close to 1000 cm"1 was observed, which is the main vibrational band of maskelynite (Palomba et al. 2006). The calculated FWHM showed the disordering rate of shocked feldspars. On the basis of the measurements it could be concluded that the estimated shock pressure range gradually increases from 17-35 GPa for different degrees of undulatory sites, to 35-45 GPa for maskelynite sites.
机译:我们用中红外光谱法(反射模式)研究了Asuka-881757,531-2样品中三种类型的冲击长石。在岩相显微镜下,三种类型的位点的特征是:(1)起伏消光,(2)具有各向同性斑块且干扰色减少的调节性消光,以及(3)各向同性的板条状长石,这表明是假牙长石。 IR发射率最大值(克里斯蒂安森特征= CF)随长石的化学组成而变化。 Christiansen的组成特征之一是钙长石的波长峰值为1234 cm〜(-1)。蒙脱石的另一个特征出现在1245 cm〜(-1)处(Palomba et al。2006)。借助红外光谱,我们在光谱中观察到三种振动类型:(1)SiO_4四面体去聚化峰(500-650 cm〜(-1),950-1150 cm〜(-1)),(2)峰SiO_6八面体(750-850 cm〜(-1))的拉伸和弯曲振动模式的变化,以及(3)SiO_4单元的Si-O拉伸振动(Johnson and Horz 2003; Johnson et al。2003,2007)。在震动较少的位置观察到所有这些振动类型。在高冲击蒙皮石的光谱中,仅观察到一个较宽的频带接近1000 cm“ 1,这是蒙皮石的主要振动带(Palomba et al。2006)。计算的FWHM显示了冲击长石的无序化率。根据测量结果,可以得出结论,估计的冲击压力范围从不同程度的起伏位置逐渐增加到17-35 GPa,而对于绿水沸石位置则增加到35-45 GPa。

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